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Voltamperometry of 1,4-dihydropyridine derivatives

III. Effect of ester groupings in the 3 and 5 positions of γ-unsubstituted 1,4-dihydropyridines on their electrooxidation potentials

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Twenty-two alkyl, alkoxyethyl, and aryl esters of 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylic acid were subjected to electrochemical oxidation on a rotating platinum microelectrode in acetonitrile. It was established that the effect of a change in the ester group on the Ep (E1/2) value is insignificant. It is assumed that the γ-carbon atom is the possible center of primary detachment of an electron.

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Literature cited

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Authors and Affiliations

  1. Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, Riga

    Ya. P. Stradyn', G. Ya. Dubur, Ya. R. Uldrikis, A. É. Sausin' & B. S. Chekavichus

  2. V. L. Lenin Khar'kov Polytechnic Institute, USSR

    Ya. P. Stradyn', G. Ya. Dubur, Ya. R. Uldrikis, A. É. Sausin' & B. S. Chekavichus

Authors
  1. Ya. P. Stradyn'
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  2. G. Ya. Dubur
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  3. Yu. I. Beilis
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  4. Ya. R. Uldrikis
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  5. A. É. Sausin'
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  6. B. S. Chekavichus
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Additional information

See [2] for communication II.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1530–1533, November, 1975.

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Stradyn', Y.P., Dubur, G.Y., Beilis, Y.I. et al. Voltamperometry of 1,4-dihydropyridine derivatives. Chem Heterocycl Compd 11, 1303–1306 (1975). https://doi.org/10.1007/BF00474459

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  • DOI: https://doi.org/10.1007/BF00474459

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