Abstract
Calculations of the electronic structure of 5-alkyl-2-thiopyrrolidones and their oxygen analogs were carried out by the MO LCAO method in the CNDO/2 approximation. The obtained data were used to discuss the reactivity of the investigated compounds in the alkylation of monochloroacetic acid, leading, in the case of 2-thiopyrrolidones, to the formation of the corresponding thiazolinones.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1690–1692, December, 1986.
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Bespalova, G.V., Sedavkina, V.A., Ponomareva, E.V. et al. Reaction of 2-thiopyrrolidones with monochloroacetic acid and its methyl ester. Chem Heterocycl Compd 22, 1370–1372 (1986). https://doi.org/10.1007/BF00474363
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DOI: https://doi.org/10.1007/BF00474363