Summary
A differential pulse polarographic method has been applied to the determination of trace concentrations of TeO 2−4 , TeO 2−3 , AsO −2 and VO −3 . The dependence of the differential pulse peak on various parameters was studied and optimum conditions for the analytical determination of these oxyanions were found. Limits of detection and quantitation have been calculated for the differential pulse polarographic determination of the investigated oxyanions. The selectivity of this technique for the determination of binary (TeO 2−4 -TeO 2−3 , TeO 2−4 -AsO −2 and TeO 2−4 -VO −3 ) mixtures and a ternary (TeO 2−4 -TeO 2−3 -AsO −2 ) mixture has also been reported.
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References
Issa RM, Abd El Naby BA (1967) Fresenius Z Anal Chem 231:339
Arnold JP, Johnson RM (1969) Talanta 16:1191
Lakhani R, Joshi AP (1984) Ind Chem Soc 61:241
Gaur JN, Bhargana SK, Sharma SK (1980) Ind Chem Soc 57:898
Lingane JJ, Meites L (1948) Am Chem Soc 69:102
Temerk YM, Kamal MM, Ahmed ME (1965) Electrochem Soc Ind 34:177
Myers DJ, Osteryoung J (1973) Anal Chem 45:267
Temerk YM, Ahmed ME, Kamal MM (1980) Fresenius Z Anal Chem 301:414
Chakraborti D, Nicholsand RL, Irgolic KJ (1984) Fresenius Z Anal Chem 319:248
Foisberg Y, O'Langhlin JW, Megargle RE (1975) Anal Chem 47:1586
Davis HP, Dulude GR, Griffin RM, Matson ZR, Zink EW (1978) Anal Chem 50:137
Holak W (1982) Anal Chem 52:2189
Britton HTS (1952) Hydrogen ions, 4th edn. Chapman and Hall, p 313
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Kamal, M.M., Ahmed, Z.A. & Temerk, Y.M. Trace determination of TeO 2−4 , TeO 2−3 , AsO −2 and VO −3 by differential pulse polarography and resolution of binary and ternary mixtures of selected oxyanions. Z. Anal. Chem. 330, 605–609 (1988). https://doi.org/10.1007/BF00473776
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DOI: https://doi.org/10.1007/BF00473776