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Synthesis and stereochemistry of 2, 2-dimethyl-5-aryl-4-benzoyl-1,3-dioxolanes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The reaction of 3-aryl-2-benzoyloxiranes with acetone in the presence of catalytic amounts of boron trifluoride etherate leads to the formation of mixtures of cis and trans isomers (∼30∶70) of 2,2-dimethyl-5-aryl-4-benzoyl-1,3-dioxolanes, the structures and stereochemistry of which were established on the basis of data from their PMR spectra, measurement of the Overhauser nuclear effect, and some chemical transformations.

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Authors and Affiliations

  1. V. I. Lenin Belorussian State University, 220080, Minsk

    O. N. Bubel', I. G. Tishchenko, G. Z. Stasevich, I. L. Romanko, A. F. Abramov & E. D. Skakovskii

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  1. O. N. Bubel'
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  2. I. G. Tishchenko
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  3. G. Z. Stasevich
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  4. I. L. Romanko
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  5. A. F. Abramov
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  6. E. D. Skakovskii
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 888–891, July, 1979.

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Bubel', O.N., Tishchenko, I.G., Stasevich, G.Z. et al. Synthesis and stereochemistry of 2, 2-dimethyl-5-aryl-4-benzoyl-1,3-dioxolanes. Chem Heterocycl Compd 15, 723–726 (1979). https://doi.org/10.1007/BF00473549

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  • DOI: https://doi.org/10.1007/BF00473549

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