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Synthesis and mass spectra of 2,3-dihydro-1H-1,5-benzodiazepine-2-thiones

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

2,3-Dihydro-1H-1,5-benzodiazepine-2-thiones and their N-methyl and S-methyl derivatives were synthesized. It was demonstrated by means of the IR, UV, PMR, and mass spectra that in solutions with different polarities 1,5-benzodiazepine-2-thiones exist primarily in the thione form; the thione and enamino-thiol forms are the most probable forms in the gas phase.

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Authors and Affiliations

  1. Dnepropetrovsk State University, 320625, Dnepropetrovsk

    Z. F. Solomko, P. A. Sharbatyan, A. A. Gaponov & V. I. Avraraenko

Authors
  1. Z. F. Solomko
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  2. P. A. Sharbatyan
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  3. A. A. Gaponov
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  4. V. I. Avraraenko
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 396–400, March, 1990.

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Solomko, Z.F., Sharbatyan, P.A., Gaponov, A.A. et al. Synthesis and mass spectra of 2,3-dihydro-1H-1,5-benzodiazepine-2-thiones. Chem Heterocycl Compd 26, 341–345 (1990). https://doi.org/10.1007/BF00472558

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  • DOI: https://doi.org/10.1007/BF00472558

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