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Stereochemistry of heterocycles

XIX. Synthesis and stereochemistry of some 4,5-dlalkyl-5-α-methoxyethyl- and 2, 2,4-trimethyl-5-alkyl-5-α-methoxyethyl-1,3-dioxanes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A number of 4-methyl-5-alkyl-5-α-methoxyethyl- and 2,2,4-trimethyl-5-α-methoxyethyl-1,3-dioxanes were synthesized. Precision rectification was used to isolate the individual stereoisomers, the configurations and preferred conformations of which were confirmed by IR and PMR spectroscopy. The reduction of the alkyl-α-methoxyethylacetoacetic esters, which gives the starting compounds for the synthesis of 1,3-dioxanes of 2-alkyl2-α-methoxyethylbutane-1, 3-diols, proceeds stereospecifically.

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Authors and Affiliations

  1. I.I. Mechnikov Odessa State University, USSR

    A. V. Bogatskii, G. F. Tantsyura & A. I. Gren'

Authors
  1. A. V. Bogatskii
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  2. G. F. Tantsyura
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  3. A. I. Gren'
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Additional information

See [1] for communication XVIII.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1475–1479, November, 1972.

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Bogatskii, A.V., Tantsyura, G.F. & Gren', A.I. Stereochemistry of heterocycles. Chem Heterocycl Compd 8, 1331–1334 (1972). https://doi.org/10.1007/BF00471864

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  • DOI: https://doi.org/10.1007/BF00471864

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