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Rearrangement of the semidine type in the indole series. Synthesis of 2-arylamino-3-acetamidoindoles

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A previously unknown (in the indole series) rearrangement of the semidine type leading leading to the formation of 1-methyl-2-arylamino-3-acetamidoindoles, the oxidation of which gives 1-methylisatin α-anils, occurs when 1-methyl-3-arylazoindoles are treated with zinc in acetic acid in the presence of acetic anhydride and sodium acetate. Data from the UV, IR, and PMR spectra are presented.

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Literature cited

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Authors and Affiliations

  1. S. Ordzhonikidze All-Union Scientific-Research Pharmaceutical-Chemistry Institute, 119021, Moscow

    G. N. Kurilo, N. I. Rostova, A. A. Cherkasova & A. N. Grinev

Authors
  1. G. N. Kurilo
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  2. N. I. Rostova
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  3. A. A. Cherkasova
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  4. A. N. Grinev
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 353–356, March, 1977.

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Kurilo, G.N., Rostova, N.I., Cherkasova, A.A. et al. Rearrangement of the semidine type in the indole series. Synthesis of 2-arylamino-3-acetamidoindoles. Chem Heterocycl Compd 13, 284–287 (1977). https://doi.org/10.1007/BF00470311

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  • DOI: https://doi.org/10.1007/BF00470311

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