Abstract
The conditions for the separation of the stereoisomeric sulfones and sulfoxides of 3-methyl-2-thiabicyclo[4.4.0]decane were found by means of capillary gas-liquid chromatography, and the relative thermodynamic stabilities of the latter were determined. The configuration of the stereoisomeric sulfoxides was established on the basis of oxidation data, the characteristics of the physicochemical properties, and the Kerr effect.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 621–624, May, 1976.
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Karaulova, E.N., Petrova, L.M., Gal'pern, G.D. et al. Conformational analysis of the stereoisomers of 3-methyl-2-oxo-2-thiabicyclo[4.4.0]decane. Chem Heterocycl Compd 12, 520–523 (1976). https://doi.org/10.1007/BF00470103
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DOI: https://doi.org/10.1007/BF00470103