Skip to main content
Log in

Elastic behaviors of swollen multiphase networks of SBS and SIS block copolymers

  • Original Contributions
  • Published:
Rheologica Acta Aims and scope Submit manuscript

Abstract

A study on the swelling properties of SBS and SIS block copolymers was reported. A new relation of the elastic properties of SBS and SIS to the structure of elastomers, the swelling ratio and the nature of selective swelling agents was derived from the statistical theory of viscoelasticity developed earlier for thermoplastic elastomers SBS(SIS). The dependence of viscoelastic free energy of deformation and state equation on the nature of swelling agents and the swelling ratio was also investigated. It shows that the statistical theory of viscoelasticity for SBS(SIS) elastomers has proven to be very useful in characterizing the elastic behavior of swollen multiphase networks of SBS and SIS.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Ceausescu E (1983) Gercetari In Chimia Si Technologia Polimerilor, Editura Academiei Republicii Socialiste Romania, Bucuresti

    Google Scholar 

  • Flory PJ, Erman B (1982) Theory of elasticity of polymer networks 3. Macromol 15:800–806

    Google Scholar 

  • Gumbrell SM, Mullins L, Rivlin RS (1953) Departures of the elastic behavior of rubbers in simple extension from the kinetic theory. Trans Faraday Soc 49:1495–1505

    Google Scholar 

  • Guth E (1945) Theory of filler reinforcement. J Appl Phys 16:20–25

    Google Scholar 

  • He ZR (1992) A statistical theory of viscoelasticity and its application for styrene-diene block copolymers-thermoplastic elastomers. PhD Dissertation, Beijing Institute of Chemical Technology, Beijing

    Google Scholar 

  • Holden G, Biop ET, Logge NR (1969) Thermoplastic elastomers. J Polym Sci C26:37–57

    Google Scholar 

  • Leonard WJ (1976) Block copolymer elasticity. J Polym Sci Polym Symp 54:237–248

    Google Scholar 

  • Mooney M (1940) A theory of large elastic deformation. J Appl Phys 11:582–592

    Google Scholar 

  • Rivlin RS (1947) Torsion of a rubber cylinder. J Appl Phys 14:444–449

    Google Scholar 

  • Ronca G, Allegra G (1975) An approach to rubber elasticity with internal constraints. J Chem Phys 63:4990–4997

    Google Scholar 

  • Song MS, He ZR (1990) The molecular theory of viscoelasticity for thermoplastic elastomers SBS(SIS) at large deformations. Rheol Acta 29:31–45

    Google Scholar 

  • Song MS, Lin HQ, Ni JL (1987) Elastic properties of swollen real polymer networks. Polymer Bulletin 18:545–552

    Google Scholar 

  • Treloar LRG (1958) The physics of rubber elasticity. 2nd ed., Oxford, Clarendon

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

He, Z.R., Song, M.S. Elastic behaviors of swollen multiphase networks of SBS and SIS block copolymers. Rheola Acta 32, 254–262 (1993). https://doi.org/10.1007/BF00434189

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00434189

Key words

Navigation