Skip to main content
Log in

Laser studies of reaction dynamics

  • Published:
Naturwissenschaften Aims and scope Submit manuscript

Abstract

Laser and molecular beam techniques allow detailed study of many dynamical properties of single reactive collisions. The chemical scope of these methods is now very wide and includes internal state preparation of reactants, change of collision energies, state detection of products, and thus determination of state-to-state reaction rates. The great impact of laser spectroscopy on knowledge in the field of structure, molecular energy transfer and the mechanism of elementary chemical reactions is illustrated by a few selected examples, including studies in which laser-induced fluorescence (LIF) has been used to to determine the polarization of reaction products

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. For a general review see Bernstein, R.B.: Chemical Dynamics via Molecular Beam and Laser Techniques. New York: Oxford Univ. Press 1982

    Google Scholar 

  2. Levy, M.R.: Progr. React. Kin. 10, 1 (1979)

    Google Scholar 

  3. Zare, R.N., Dagdigian, P.J.: Science 185, 739 (1974)

    Google Scholar 

  4. Engelke, F.: Ber. Bunsenges. Phys. Chem. 81, 135 (1977)

    Google Scholar 

  5. Kinsey, J.L.: Ann. Rev. Phys. Chem. 28, 349 (1977)

    Google Scholar 

  6. Engelke, F.: Comments Atom. Mol. Phys. 11, 13 (1981)

    Google Scholar 

  7. Silvers, S.J., Gottscho, R.A., Field, R.W.: J. Chem. Phys. 74, 6000 (1981)

    Google Scholar 

  8. Hurst, G.S., Nayfeh, M.H., Young, J.P.: Appl. Phys. Lett. 30, 229 (1977)

    Google Scholar 

  9. Beck, D., et al.: Forschungsber. des Landes Nordrhein-Westfalen Nr. 3096. Opladen: Westdeutscher Verlag 1982

    Google Scholar 

  10. Gupta, A., Perry, D.S., Zare, R.N.: J. Chem. Phys. 72, 6237 (1980)

    Google Scholar 

  11. Odiorne, T.J., Brooks, R.P., Kasper, J.V.V.: ibid. 55, 1980 (1971)

    Google Scholar 

  12. Pruett, J.G., Zare, R.N.: ibid. 64, 1774 (1976)

    Google Scholar 

  13. Torres-Filho, A., Pruett, J.G.: ibid. 72, 6736 (1980)

    Google Scholar 

  14. Torres-Filho, A., Pruett, J.G.: ibid. 77, 740 (1982)

    Google Scholar 

  15. Engelke, F.: Chem. Phys. 39, 279 (1979)

    Google Scholar 

  16. Engelke, F.: ibid. 44, 213 (1979)

    Google Scholar 

  17. Meiwes-Broer, K.H.: Dissertation Univ. Bielefeld 1983

  18. Gupta, A., Perry, D.S., Zare, R.N.: J. Chem. Phys. 72, 6736 (1980)

    Google Scholar 

  19. Karny, Z., Zare, R.N.: ibid. 68, 3360 (1978)

    Google Scholar 

  20. Case, D.A., McClelland, G.M., Herschbach, D.R.: Mol. Phys. 35, 541 (1978)

    Google Scholar 

  21. Hijazi, N.H., Polanyi, J.C.: J. Chem. Phys. 63, 2249 (1975)

    Google Scholar 

  22. Hijazi, N.H., Polanyi, J.C.: Chem. Phys. 11, 1 (1975)

    Google Scholar 

  23. Hsu, D.S.Y., McClelland, G.M., Herschbach, D.R.: J. Chem. Phys. 61, 4927 (1974)

    Google Scholar 

  24. Engelke, F., Hage, H., Schühle, U.: to be published

  25. Hermann, A., et al.: Helv. Chim. Acta 61, 453 (1978)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

It is a pleasure to thank first my coworkers devoted to these studies of reaction dynamics, H. Ellerbusch, H. Hage, K.H. Meiwes-Broer, and U. Schühle. In addition, I thank D. Beck and R.N. Zare (Stanford) for their comments and suggestions. I wish to acknowledge support of my work by the Deutsche Forschungsgemeinschaft and the Minister für Wissenschaft und Forschung des Landes Nordrhein-Westfalen.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Engelke, F. Laser studies of reaction dynamics. Naturwissenschaften 70, 594–601 (1983). https://doi.org/10.1007/BF00377401

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00377401

Keywords

Navigation