Skip to main content
Log in

Conditions of metamorphism in an early Paleozoic blueschist, schist of Skookum Gulch, northern California

  • Published:
Contributions to Mineralogy and Petrology Aims and scope Submit manuscript

Abstract

The Late Ordovician schist of Skookum Gulch, northern California, is one of only a few pre-Mesozoic blueschist localities in North America. Among these, the Skookum Gulch occurrence is noteworthy because it contains lawsonite and has had a relatively simple metamorphic and structural history.

Numerous assemblages and a wide variation in the modal proportion of minerals are present due to a spectrum of bulk compositions. This is reflected in the composition of Na-amphibole, which varies from ferro-glaucophane, glaucophane, and crossite (±magnetite) to magnesio-riebeckite (+hematite). Application of the available experiments and empirically calibrated equilibria to the assemblages glaucophane+lawsonite+chlorite+quartz+albite and glaucophane+actinolite+epidote+chlorite+quartz+albite yield estimates of temperature and pressure near T= 275° C and P=7.0 kbar. Estimates of uncertainty are difficult to assess, but are no more than ±100° C and ±3.0 kbar, and are probably considerably smaller. Calcite +quartz+sphene and calcite+quartz+actinolite indicate an extremely H2O-rich fluid (X(CO2)<0.003).

The absence of a greenschist facies overprint indicates that the schist of Skookum Gulch was uplifted soon after metamorphism. However, it was not exposed until the recent geologic past, having resided at shallow crustal levels for approximately 400 Ma.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Albee AL, Ray L (1970) Correction methods for electron probe microanalysis of silicates, oxides, carbonates, phosphates, and sulfates. Anal Chem 42:1408–1414

    Google Scholar 

  • Armstrong RL, Harakal JE, Brown EH, Bernardi ML, Rady PM (1983) Late Paleozoic high-pressure metamorphic rocks in northwestern Washington and southwestern British Columbia: the Vedder complex. Geol Soc Am Bull 94:451–458

    Google Scholar 

  • Armstrong RL, Harakal JE, Forbes RB, Evans BW, Thurston SP (1986) Rb-Sr and K-Ar study of metamorphic rocks of the Seward Peninsula and southern Brooks Range, Alaska. Geol Soc Am Mem 164:185–203

    Google Scholar 

  • Bence AE, Albee AL (1968) Empirical correction factors for the electron microanalysis of silicates and oxides. J Geol 76:382–403

    Google Scholar 

  • Black PM (1975) Mineralogy of New Caledonian metamorphic rocks. IV. Sheet silicates from the Oúegoa district. Contrib Mineral Petrol 49:269–284

    Google Scholar 

  • Brown EH (1971) Phase relations of biotite and stilpnomelane in the greenschist facies. Contrib Mineral Petrol 31:275–299

    Google Scholar 

  • Brown EH (1974) Comparison of the mineralogy and phase relations of blueschists from the North Cascades, Washington, and greenschists from Otago, New Zealand. Geol Soc Am Bull 85:333–344

    Google Scholar 

  • Brown EH (1977) The crossite content of Ca-amphibole as a guide to pressure of metamorphism. J Petrol 18:53–72

    Google Scholar 

  • Brown EH, Ghent ED (1983) Mineralogy and phase relations in the blueschist facies of the Black Butte and Ball Rock areas, northern California Coast Ranges. Am Mineral 68:365–372

    Google Scholar 

  • Burnham CW, Holloway JR, Davis NF (1969) Thermodynamic properties of water to 1,000° C and 10,000 bars. Geol Soc Am Spec Pap 132:96

    Google Scholar 

  • Carlson WD, Rosenfeld JL (1981) Optical determination of topotactic aragonite-calcite growth kinetics: metamorphic implications. J Geol 89:615–638

    Google Scholar 

  • Cashman SM (1980) Devonian metamorphic event in the northeastern Klamath Mountains, California. Geol Soc Am Bull 91:453–459

    Google Scholar 

  • Cloos M (1985) Thermal evolution of convergent plate margins: thermal modeling and reevaluation of isotopic Ar-ages for blueschists in the Franciscan complex of California. Tectonics 4:421–433

    Google Scholar 

  • Coleman RG, Papike JJ (1968) Alkali amphiboles from the blueschists of Cazadero, California. J Petrol 9:105–122

    Google Scholar 

  • Cotkin ML, Cotkin SJ (1985) Structural style, metamorphism, and tectonic implications of early Paleozoic blueschist, eastern Klamath Mountains. Geol Soc Am 17:349

    Google Scholar 

  • De Roever WP (1956) Some differences between post-Paleozoic and older regional metamorphism. Geol Mijnbouw 18:123–127

    Google Scholar 

  • De Roever WP (1964) On the cause of the preferential distribution of certain metamorphic minerals in orogenic belts of different age. Geol Rundsch 54:933–943

    Google Scholar 

  • Draper G, Bone R (1981) Denudation rates, thermal evolution, and preservation of blueschist terrains. J Geol 89:601–613

    Google Scholar 

  • Ernst WG (1963) Significance of phengitic micas from low grade schist. Am Mineral 48:1357–1373

    Google Scholar 

  • Ernst WG (1972a) Occurrence and mineralogic evolution of blueschist belts with time. Am J Sci 272:657–668

    Google Scholar 

  • Ernst WG (1972b) CO2-poor composition of the fluid attending Franciscan and Sanbagawa low-grade metamorphism. Geochim Cosmochim Acta 36:497–504

    Google Scholar 

  • Ernst WG (1973) Blueschist metamorphism and P-T regimes in active subducton zones. Tectonophysics 17:255–272

    Google Scholar 

  • Ernst WG (1979) Coexisting sodic and calcic amphiboles from high-pressure metamorphic belts and the stability of barroisitic amphibole. Mineral Mag 43:269–278

    Google Scholar 

  • Goldsmith JR, Jenkins DM (1985) The hydrothermal melting of low and high albite. Am Mineral 70:924–933

    Google Scholar 

  • Helgeson HC, Delaney JM, Nesbitt HW, Bird DK (1978) Summary and critique of the thermodynamic properties of rock-forming minerals. Am J Sci 278A:1–229

    Google Scholar 

  • Henry DJ, Guidotti CV (1985) Tourmaline as a petrogenetic indicator mineral: an example from the staurolite-grade metapelites of NW Maine. Am Mineral 70:1–15

    Google Scholar 

  • Holland TJB (1979) Experimental determination of the reaction paragonite=jadeite+kyanite+H2O, and internally consistent thermodynamic data for part of the system Na2O-Al2O3-SiO2-H2O, with applications to eclogites and blueschists. Contrib Mineral Petrol 68:293–301

    Google Scholar 

  • Holland TJB (1980) The reaction albite=jadeite+quartz determined experimentally in the range 600–1200° C. Am Mineral 65:129–134

    Google Scholar 

  • Holland TJB (1983) The experimental determination of activities in disordered and short-range ordered jadeitic pyroxenes. Contrib Mineral Petrol 82:214–220

    Google Scholar 

  • Hunt JA, Kerrick DM (1977) The stability of sphene; experimental redetermination and geologic implications. Geochim Cosmochim Acta 41:279–288

    Google Scholar 

  • Irwin WP (1981) Tectonic accretion of the Klamath Mountains. In: Ernst WG (ed) The geotectonic development of California (Rubey Vol 1). Prentice-Hall, Englewood Cliffs, New Jersey, pp 29–49

    Google Scholar 

  • Johannes W, Puhan D (1971) The calcite-aragonite transition, reinvestigated. Contrib Mineral Petrol 31:28–38

    Google Scholar 

  • Kerrick DM, Jacobs GK (1981) A modified Redlich-Kwong equation for H2O, CO2, and H2O-CO2 mixtures at elevated pressures and temperatures. Am J Sci 281:735–767

    Google Scholar 

  • Koons PO (1982) Experimental investigation of the behavior of amphibole in the system Na2O-MgO-Al2O3-SiO2-H2O at high pressures. Contrib Mineral Petrol 79:258–267

    Google Scholar 

  • Laird J, Albee AL (1981) High-pressure metamorphism in mafic schists from northern Vermont. Am J Sci 281:97–126

    Google Scholar 

  • Lindsley-Griffin N, Griffin JR (1983) The Trinity terrane: an early Paleozoic microplate assemblage. In: Stevens CH (ed) Pre-Jurassic rocks in western North American suspect terranes. Society of Economic Paleontolgists and Mineralogists, Los Angeles, pp 63–72

    Google Scholar 

  • Liou JG, Maruyama S, Cho M (1985) Phase equilibria and mineral parageneses of metabasites in low-grade metamorphism. Mineral Mag 49:321–333

    Google Scholar 

  • Maresch WV (1977) Experimental studies of glaucophane: an analysis of present knowledge. Tectonophysics 43:109–125

    Google Scholar 

  • Maruyama S, Liou JG, Saskura Y (1985) Low-temperature recrystallization of Franciscan greywackes from Pacheco Pass, California. Mineral Mag 49:345–355

    Google Scholar 

  • Maruyama S, Cho M, Liou J (1986) Experimental investigations of blueschist-greenschist transition equilibria: pressure dependence of Al2O3 contents in sodic amphibole — a new geobarometer. Geol Soc Am Spec Pap 164:1–16

    Google Scholar 

  • Nakajima T, Banno S, Suzuki T (1977) Reactions leading to the disappearance of pumpellyite in low-grade metamorphic rocks of the Sanbagawa metamorphic belt in Central Shikoku, Japan. J Petrol 18:263–284

    Google Scholar 

  • Newton RC, Smith JV (1967) Investigations concerning breakdown of albite at depth in the earth. J Geol 75:268–286

    Google Scholar 

  • Nitsch KH (1968) Die Stabilität von lawsonite. Naturwissenschaften 55:38

    Google Scholar 

  • Okay AI (1979) Sodic amphiboles as oxygen fugacity indicators in metamorphism. J Geol 88:225–232

    Google Scholar 

  • Potter AW, Hotz PE, Rohr DM (1977) Stratigraphy and inferred tectonic framework of lower Paleozoic rocks in the eastern Klamath Montains, northern California. In: Stewart JH, Stevens CH, Fritsche AE (eds) Paleozoic paleogeography of the western United States. Society of Economic Paleontologists and Mineralogists, Los Angeles, pp 421–440

    Google Scholar 

  • Potter AW, Hotz PE, Lanphere M (1981) Evidence of OrdovicianSilurian subduction and Silurian or older igneous units of possible magmatic arc origin, eastern Klamath Mountains, northern California. Geol Soc Am 13:101

    Google Scholar 

  • Robie RA, Hemingway BS, Fisher JR (1978) Thermodynamic properties of minerals and related substances at 298.15 K and 1 bar (105 Pascals) pressure and at higher temperatures. US Geol Surv Bull 1452:456

    Google Scholar 

  • Slaughter J, Kerrick DM, Wall VJ (1975) Experimental and thermodynamic study of equilibria in the system CaO-MgO-SiO2-H2O-CO2. Am J Sci 275:143–162

    Google Scholar 

  • Thurston SP (1985) Structure, petrology, and metamorphic history of the Nome Group blueschist terrane, Salmon Lake area, Seward Peninsula, Alaska. Geol Soc Am Bull 96:600–617

    Google Scholar 

  • Toriumi M (1974) Actinolite-alkali amphibole miscibility gap in an amphibole composite-grain in a glaucophane schist facies rock, Kanto Mountains, Japan. J Geol Soc Jpn 80:75–80

    Google Scholar 

  • Trzcienski WE, Carmichael DM, Helmstaedt H (1984) Zoned sodic amphibole: petrologic indicator of changing pressure and temperature during tectonism in the Bathurst area, New Brunswick, Canada. Contrib Mineral Petrol 85:311–320

    Google Scholar 

  • Turner DL, Forbes RB, Dillon JT (1979) K-Ar geochronology of the southwestern Brooks Range, Alaska. Can J Earth Sci 16:1789–1804

    Google Scholar 

  • Valley JW, Essene EJ (1972) Calc-silicate reactions in Adirondack marbles: the role of fluids and solid solution. Geol Soc Am Bull 91:114–117, 720–815

    Google Scholar 

  • Wall VJ, Essene EJ (1980) Subsolidus equilibria in CaO-Al2O3-SiO2-H2O. Geol Soc Am 4:700

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Cotkin, S.J. Conditions of metamorphism in an early Paleozoic blueschist, schist of Skookum Gulch, northern California. Contr. Mineral. and Petrol. 96, 192–200 (1987). https://doi.org/10.1007/BF00375233

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00375233

Keywords

Navigation