Abstract
The viscosities of supercooled melts of 13 different plagioclase compositions have been measured in the range 1013–108 dPas with a micro-penetration viscometer. Application of the most common empirical and theoretical viscosity-temperature models to the present data and plagioclase viscosity data available from the literature showed that the configurational entropy theory represents the best approach. Using this theory together with an entropy of mixing term evaluated from a modified “two-lattice” mixing model, the viscosities of intermediate plagioclase compositions have been calculated as a function of temperature and anorthite content solely from the appropriate data of the end members albite and anorthite. The agreement between experimental and calculated viscosity data is excellent.
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References
Adam G, Gibbs JH (1965) On the temperature dependence of co-operative relaxation properties in glass-forming liquids. J Chem Phys 43:139–146
Angell CA, Cheeseman P, Tamaddon S (1983) Water-like transport property anomalies in liquid silicates investigated at high T and P by computer simulation techniques. Bull Mineral 106:87–97
Arndt J, Häberle F (1973) Thermal expansion and glass transition temperature of synthetic glasses of plagioclase-like compositions. Contrib Mineral Petrol 39:175–183
Arndt J, Hummel W (1983) A micro-penetration viscometer for the viscosity range 103–107 poise. Fortschr Min 61 Beiheft 1:9–10
Arndt J, Hummel W, Gonzalez-Cabeza I (1982) Diaplectic labradorite glass from the Manicouagan impact crater. Phys Chem Minerals 8:230–239
Bottinga Y, Weill DF (1972) The viscosity of magmatic silicate liquids: A model for calculation. Am J Sci 272:438–475
Brückner R, Demharter G (1975) Systematische Untersuchungen über die Anwendbarkeit von Penetrationsviskosimetern. Glastechn Ber 48:12–18
Cranmer D, Uhlmann DR (1981a) Viscosity of liquid albite, a network material. J Non-Cryst Solids 45:283–288
Cranmer D, Uhlmann DR (1981b) Viscosities in the system albiteanorthite. J Geophys Res 86:7951–7956
Cukiermann M, Uhlmann DR (1973) Viscosity of liquid anorthite. J Geophys Res 78:4920–4923
Jong HWS de, Schramm CM, Parziale VE (1983) Polymerization of silicate and aluminate tetrahedra in glasses, melts, and aqueous solutions — IV. Aluminum coordination in glasses and aqueous solutions and comments on the aluminum avoidance principle. Geochim Cosmochim Acta 47:1223–1236
Dietz ED, Baak T, Blau HH (1970) The superheating of an albite feldspar. Z Kristallogr 132:340–360
Exnar P, Voldán J (1982) Measuring viscosity with the penetration viscometer I. Silikáty 26:251–259
Henry DJ, Navrotsky A, Zimmermann HD (1982) Thermodynamics of plagioclase-melt equilibria in the system albite-anorthitediopside. Geochim Cosmochim Acta 46:381–391
Hofmaier G, Urbain G (1968) The viscosity of pure silica. Science of Ceramics Vol 4:25–32, Edited by GH Stewart, British Ceramic Society, Stoke-on-Trent, 1968
Kushiro I (1978) Viscosity and structural change of albite (NaAl· Si3O8) melt at high pressure. Earth Planet Sci Lett 41:87–90
Kushiro I (1981) Change in viscosity with pressure of melts in the system CaO-Al2O3-SiO2. Carnegie Inst Wash Yearb 80:339–341
Moore WJ, Hummel DO (1976) Physikalische Chemie 2. Auflage Walter de Gruyter-Verlag, Berlin New York
Mysen BO, Virgo D, Seifert FA (1982) The structure of silicate melts: Implications for chemical and physical properties of natural magma. Rev Geophys Space Phys 20:353–383
Richet P (1984) Viscosity and configurational entropy of silicate melts. Geochim Cosmochim Acta 48:471–483
Richet P, Bottinga Y (1983) Verres, liquides et transition vitreuse. Bull Minéral 106:147–168
Richet P, Bottinga Y (1984) Anorthite, andesine, wollastonite, diopside, cordierite and pyrope: thermodynamics of melting, glass transition, and properties of the amorphous phases. Earth Planet Sci Lett 67:415–432
Scarfe CM, Cronin DJ, Wenzel JT, Kauffman DA (1983) Viscosity-temperature relationships at 1 atm in the system diopside-anorthite. Am Mineral 68:1083–1088
Scherer GW (1984) Use of the Adam-Gibbs equation in the analysis of structural relaxation. J Am Ceram Soc 67:504–511
Sturm KG (1980) Zur Temperaturabhängigkeit der Viskosität von Flüssigkeiten. Glastechn Ber 53:63–76
Taylor TD, Rindone GE (1970) Properties of soda aluminosilicate glasses: V, Low-temperature viscosities. J Am Ceram Soc 53:692–695
Urbain G, Bottinga Y, Richet P (1982) Viscosity of liquid silica, silicates and alumino-silicates. Geochim Cosmochim Acta 46:1061–1072
Weill DF, Hon R, Navrotsky A (1980) The igneous system CaMg· Si2O6-CaAlSi2O8-NaAlSi3O8: Variations on a classical theme by Bowen. In: Hargraves RB (ed) Physics of Magmatic Processes. Princeton Univ Press, pp 49–92
Wilder JA, Shelby JE (1984) Property variation in alkali alkaline-earth metaphosphate glasses. J Am Ceram Soc 67:438–444
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Dedicated to Professor Wolf von Engelhardt on the occasion of his 75th birthday
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Hummel, W., Arndt, J. Variation of viscosity with temperature and composition in the plagioclase system. Contr. Mineral. and Petrol. 90, 83–92 (1985). https://doi.org/10.1007/BF00373044
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DOI: https://doi.org/10.1007/BF00373044