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Effect of MnO, CaO and nitrogen on the alkaline durability of soda-lime silicate glasses

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Abstract

MnO containing soda-lime silicate glasses were vitrified and nitrogen was introduced into them. The prepared glasses were subject to density measurement and alkaline durability tests. MnO addition caused poorer alkaline durability in 2N NaOH solution at 82°C. Needle-like precipitations were observed on the MnO containing glass surface after 96 h durability tests. Glass components were found to dissolve selectively in the alkaline solution in the order SiO2 > CaO > MnO. The density of the obtained glasses increased linearly with increasing amount of nitrogen content in the glasses. A considerable improvement in alkaline durability of the glasses by nitrogen addition was observed, and its effect was larger for the MnO-free glasses.

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References

  1. K. L. Biryukovitch and Y. L. Biryukovitch, Stroit Materialy 2 (1961) 18.

    Google Scholar 

  2. A. J. Majumdar and J. F. Ryder, Glass Technol. 9 (1968) 78.

    CAS  Google Scholar 

  3. J. Jones, Glass Ind. 6 (1977) 26.

    Google Scholar 

  4. F. R. Bacon and F. C. Ragon, J. Am. Ceram. Soc. 42 (1959) 199.

    Article  CAS  Google Scholar 

  5. Y. Suzuki, Seramikkusu 11 (1976) 604.

    CAS  Google Scholar 

  6. A. J. Majumdar, J. M. West and L. J. Larner, J. Mater. Sci. 12 (1977) 927.

    Article  CAS  Google Scholar 

  7. L. J. Larner, K. Speakman and A. J. Majumdar, J. Non-Cryst. Solids 20 (1976) 43.

    Article  CAS  Google Scholar 

  8. K. Inoue, O. Matsuda, M. Daimon and R. Kondou, Yogyokyokaishi 88 (1980) 88.

    Google Scholar 

  9. M. Nogami and Y. Moriya, ibid. 85 (1977) 448.

    CAS  Google Scholar 

  10. K. Kamiya, S. Sakka and Y. Tatemichi, J. Mater. Sci. 15 (1980) 1765.

    Article  CAS  Google Scholar 

  11. K. Sakai, Seramikkusu 23 (1988) 214.

    Google Scholar 

  12. A. Paul and A. Youssefi, J. Mater. Sci. 13 (1978) 97.

    Article  CAS  Google Scholar 

  13. A. Makishima and T. Shimohira, J. Non-Cryst. Solids 38, 39 (1980) 661.

    Article  Google Scholar 

  14. G. H. Frischat and K. Sebastian, J. Am. Ceram. Soc. 68 (1985) C305.

    Article  Google Scholar 

  15. A. Makishima, M. Mitomo, H. Tanaka, N. Ii and M. Tsutsumi, in “Proceedings of the 56th Annual Meeting of the Ceramic Society of Japan” (The Ceramic Society of Japan, Tokyo, 1981) p. 47.

    Google Scholar 

  16. S. Sakka, K. Komori, H. Kozuka, T. Kokubo and N. Sugimoto, Rivista della Staz. Sper. Vetro 6 (1986) 75.

    Google Scholar 

  17. M. Rajaram and D. E. Day, J. Am. Ceram. Soc. 70 (1987) 203.

    Article  CAS  Google Scholar 

  18. B. C. Bunker and G. W. Arnold, ibid. 70 (1987) 425.

    Article  CAS  Google Scholar 

  19. J. W. Wald, D. R. Messier and E. J. Deguire, Int. J. High Technol. Ceram. 2 (1986) 65.

    Article  CAS  Google Scholar 

  20. H. Ohta and Y. Suzuki, Am. Ceram. Soc. 57 (1978) 602.

    CAS  Google Scholar 

  21. R. Wusirika, J. Am. Ceram. Soc. 74 (1991) 454.

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Faculty of Engineering, University of Tokyo, Hongo, Bunkyo-ku, 113, Tokyo, Japan

    K. Morita, A. Suganuma & A. Makishima

Authors
  1. K. Morita
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  2. A. Suganuma
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  3. A. Makishima
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Morita, K., Suganuma, A. & Makishima, A. Effect of MnO, CaO and nitrogen on the alkaline durability of soda-lime silicate glasses. JOURNAL OF MATERIALS SCIENCE 29, 6587–6591 (1994). https://doi.org/10.1007/BF00354025

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