Abstract
Glass fibres of the ZrO2-SiO2 and Na2O-ZrO2-SiO2 systems containing up to 33 wt% ZrO2 were prepared by a non-melting technique using zirconium n-propoxide, sodium methoxide and silicon tetraethoxide as raw materials. The mixed alkoxide solutions were exposed to moist air for hydrolysis. The fibrous gels were drawn from these solutions in the course of hydrolysis, and converted to the corresponding oxide glass fibres by heating at 500 to 700° C. It was found that chemical durability of the fibres toward alkaline solution increased with ZrO2 content. The weight loss due to the corrosion by 2 N NaOH solution at 96° C for 4 h was around 14 mg dm−2 for the fibres containing 17 to 26 wt% ZrO2, which was comparable to the alkali-resistant glasses so far obtained by the conventional melting technique. The glass fibres containing 33 wt% ZrO2 showed higher resistance.
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References
H. Dislich, Glastech. Ber. 44 (1971) 1.
Idem, Angew. Chem. Int. Edn. 10 (1971) 363.
S. P. Mukherjee, J. Zarzycki and J. P. Traverse, J. Mater. Sci. 11 (1976) 341.
K. Kamiya, S. Sakka and I. Yamanaka, Proceedings of the 10th International Conference on Glass (1974) (Japan Ceramic Society, Tokyo, 1974) Vol. 13, p. 44.
S. Sakka and K. Kamiya, Proceedings of the Japan-US Joint Seminor on Basic Science and Ceramics (1975) edited by W. Komatsu (Tokyo Institute of Technology, Tokyo, 1975) p. 85.
M. Nogami and Y. Moriya, Yogyo-Kyokai-Shi, (J. Ceram. Soc. Japan) 85 (1977) 59.
Idem, ibid 85 (1977) 448.
Idem, ibid 87 (1979) 37.
G. Carturam, V. Gottardi and M. Graziani, J. Non-Cryst. Solids 29 (1978) 41.
B. E. Yoldas, J. Mater. Sci. 12 (1977) 1203.
M. Yamane, S. Aso, S. Okano and T. Sakaino, ibid 14 (1979) 607.
M. Yamane and S. Okano, Yogyo-Kyokai-Shi, (J. Ceram. Soc. Japan) 87 (1979) 434.
M. Decottignies, J. Phalippou and J. Zarzycki, J. Mater. Sci. 13 (1978) 2605.
K. Kamiya, S. Sakka and N. Tashiro, Yogyo-Kyokai-Shi (J. Ceram. Soc. Japan) 84 (1976) 614.
K. Kamiya and S. Sakka, Res. Rep. Fac. Eng. Mie University 2 (1977) 87.
K. Kamiya, S. Sakka and S. Ito, Yogyo-Kyokai-Shi (J. Ceram. Soc. Japan) 85 (1977) 599.
S. Sakka and K. Kamiya, Proceedings of the International Symposium of Factors in Densification and sintering of Oxide and Non-oxide Ceramics, Japan (1978) edited by S. Somiya and S. Saito (Tokyo Institute of Technology, Tokyo, 1978) p. 101.
K. Kamiya, S. Sakka and M. Mizutani, Yogyo-Kyokai-Shi, (J. Ceram. Soc. Japan) 86 (1978) 554.
T. Baak, C. F. Rapp, H. T. Hartley and B. E. Wiens, Amer. Ceram. Soc. Bull. 47 (1968) 727.
Y. Suzuki, Seramikusu (Ceramics) 11 (1976) 604.
A. Paul, J. Mater. Sci. 12 (1977) 2246.
H. Ohta and Y. Suzuki, Amer. Ceram. Soc. Bull. 57 (1978) 602.
A. J. Majumdar and J. F. Ryder, Glass Tech. 9 (1968) 78.
L. J. Larner, K. Speakman and A. J. Majumdar, J. Non-Cryst. Solids 20 (1976) 43.
K. Kamiya and S. Sakka, Yogyo-Kyokai-Shi (J. Ceram. Soc. Japan) 85 (1977) 308.
T. Kishii and N. Ogino, “Glass Handbook”, edited by S. Sakka, T. Sakaino and K. Takahashi (Asakura Shoten, Tokyo, 1975) p. 591.
T. Boyd, J. Polymer Sci. 7 (1951) 591.
M. Yamane, S. Aso and T. Sakaino, J. Mater. Sci. 13 (1978) 865.
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Kamiya, K., Sakka, S. & Tatemichi, Y. Preparation of glass fibres of the ZrO2-SiO2 and Na2O-ZrO2-SiO2 systems from metal alkoxides and their resistance to alkaline solution. J Mater Sci 15, 1765–1771 (1980). https://doi.org/10.1007/BF00550596
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DOI: https://doi.org/10.1007/BF00550596