Abstract
Enhanced mesophase yield was achieved for A-240 pitch by addition of aromatic hydrocarbon compounds (anthracene and acenaphthylene) as nucleating agents. A-240 pitch was acid/solvent extracted prior to adding the aromatic hydrocarbons. The mesophase yields increased by significant amounts at 1 wt% addition of the nucleating agents, but decreased at 3 wt% addition. A source of Brönsted acids was required to initiate the catalytic reaction enhancing the mesophase formation.
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I. MOCHIDA, Y. KORAI, M. NAKAMURA, S. M. ZENG and M. KAMEYAMA, Carbon 27 (1989) 498.
I. MOCHIDA, Y. KORAI, M. NAKAMURA, S. IN and B. RHEE, J. Mater. Sci. Lett. 10 (1991) 121.
W. C. STEVENS and R. J. DIEFENDORF, in “Carbon 86”, Proceedings of an International Conference on Carbon (German Ceramic Society, Baden-Baden, 1986) p. 61.
J. D. BROOKS and G. H. TAYLOR, in “Chemistry and Physics of Carbon”, Vol. 4, edited by P. L. WALKER Jr (Marcel Dekker, New York, 1986) p. 243.
Y. KORAI, M. NAKAMURA, I. MOCHIDA, Y. SAKAI and S. FUJIYAMA, in “20th Biennial Conference on Carbon”, Santa Barbara, CA, (Amer. Carbon Soc., CA, Extended Abstracts, 1991) p. 158.
H. MARSH, J. M. FORSTER, G. HERMAN and M. ILEY, Fuel 52 (1973) 234.
S. H. CRANMER, I. G. PLOTZKER, L. H. PEEBLES Jr and D. R. UHLMANN, Carbon 21 (1983) 201.
I. C. LEWIS, in “20th Biennial Conference on Carbon, Extended Abstracts”, Santa Barbara, CA, (Amer. Carbon Soc., CA, 1991) p. 156.
I. MOCHIDA, T. OYAMA, Y. KORAI and Y. Q. FEI, Fuel 67 (1988) 1171.
E. FITZER, K. MUELLER and W. SCHAEFER, in “Chemistry and Physics of Carbon”, Vol. 7, edited by P. L. WALKER Jr (Dekker, New York, 1971) p. 237
Y. S. LIM and B. I. LEE, Carbon 27 (1989) 739.
I. MOCHIDA, K. SHIMIZU, Y. KORAI, H. OTSUKA and S. FUJIYAMA, in “Carbon '88”, Proceedings of the International Conference on Carbon, edited by B. MCENANEY and T. J. MAYS, University of Newcastle upon Tyne, UK (Joint carbon group of the Institute of Physics and the Royal Soc. of Chem., 1988) p. 259.
I. MOCHIDA, H. TOSHIMA, Y. KORAI and T. MATSUMOTO, J. Mater. Sci. 23 (1988) 670.
I. MOCHIDA, H. TOSHIMA, Y. KORAI and T. NAITO, ibid. 23 (1988) 678.
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Lim, Y.S., Lee, B.I. Enhanced mesophase formation of petroleum pitch by polyaromatic hydrocarbon addition. JOURNAL OF MATERIALS SCIENCE 28, 3741–3748 (1993). https://doi.org/10.1007/BF00353172
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DOI: https://doi.org/10.1007/BF00353172