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Conversion-electron Mössbauer spectroscopy using 121Sb and a study of powdered α-Sb2O3

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Abstract

It is shown that 121Sb Conversion-Electron Mössbauer Spectroscopy (CEMS) is possible even at room temperature. The parameters and peculiarities of 121Sb CEMS are summarized. An application to powdered Sb(III) oxide shows that the material on the surface of the grains is not oxidized to Sb(V) but has changed its crystal symmetry, while the bulk of the grains still exhibits the initial cubic-crystal phase.

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Authors and Affiliations

  1. Institut für Anorganische und Analytische Chemie, Universität Mainz, D-55099, Mainz, Germany

    W. Meisel

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  1. W. Meisel
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Dedicated to Prof. P. Gütlich on the occasion of his 60th birthday

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Meisel, W. Conversion-electron Mössbauer spectroscopy using 121Sb and a study of powdered α-Sb2O3 . Appl. Phys. A 59, 381–384 (1994). https://doi.org/10.1007/BF00331715

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  • DOI: https://doi.org/10.1007/BF00331715

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