Abstract
In an interlaboratory study, 57 elements were assayed and 35 of them determined in cigarette smoke condensate of two different cigarette brands. The methods applied included inductively coupled plasma mass spectrometry, total reflection X-ray fluorescence analysis, instrumental neutron activation analysis and atomic absorption spectrometry. The main components carbon, hydrogen and nitrogen were determined by a CHN-combustion method. Sulphur was determined by a method based on the formation of hydrogen sulphide and precipitation micro-titrimetry. Considering the occurring concentrations and the toxicity, the most relevant elements in cigarette smoke condensate are arsenic, cadmium and lead which have relatively high transfer rates from tobacco into smoke.
Similar content being viewed by others
References
Zimmerli B (1985) Mitt Gebiete Lebensm Hyg 76:515–530
Pesch HJ, Kraus T, Palesch T, Seibold H (1991) Progr Histo-Cytochem 23:365–371
Pesch HJ, Kraus T, Biermann K, Krapp B (1992) Fresenius J Anal Chem 343:150–151
Schmidt JA, Fischbach ED, Burkart F (1985) Z Lebensm Unters Forsch 180:306–311
Krivan V, Schaldach G (1986) Fresenius Z Anal Chem 324:158–167
Krivan V, Schaldach G, Hausbeck R (1987) Naturwissenschaften 74:242–244
Schneider G, Krivan V (1993) Intern J Environ Anal Chem 53:87–100
Nadkarni RA (1974) Chemistry and industry 17:693–696
Jenkins RW, Goldey C, Williamson TG (1985) Beiträge zur Tabakforschung International 13(2):59–65
El-Amri FA, Saleh AI, El-Gnidy BA (1989) J Radioanal Nucl Chem Letters 135(4):273–279
Igarshi Y, Yamakawa R, Oki Y, Seki R, Ikeda N (1989) J Radioanal Nucl Chem Letters 135(3):157–164
Chakarvarti SK, Dhiman J, Nagpaul KK (1978) Health Physics 36:638–640
Mishra UC, Shaikh GN (1985) J Radioanal Nucl Chem Art 89(2):545–552
Tey Nsan Yen MSHA, Wood AKH (1987) J Sains Nuclear Malays 5(2):59–64
Nadkarni RA, Ehmann WD (1970) Radiochemical and Radioanalytical Letters 4:325–335
Abedinzadeh Z, Razeghi M, Parsa B (1977) J Radioanal Chem 35:373–376
Schelenz R, Fischer E (1984) Zeitschrift für Lebensmittelunter-suchung und Forschung 178:118–119
Jenkins RW, Newman RH, Ikeda RM, Carpenter RD, Williamson TG (1971) Analytical Lett 4(7):451–457
Nadkarni RA, Ehmann WD (1970) Proc Tobacco and Health Conference Lexington, Vol 3. Lexington, pp 37–45
Nadkarni RA, Ehmann WD, Burdick D (1970) Tobacco Science 14:37–39
Iskander FY (1985) J Radionanal Nucl Chem Art 91(1):191–196
Schormüller J (1970) Alkaloidhaltige Genußmittel, Gewürze, Kochsalz. Springer, Berlin Heidelberg New York, pp 311–347
Rothwell K, Grant CA (1974) Tobacco Research Council London 11, 2nd ed
Moehnle K, Krivan V, Grallath E (1984) Fresenius Z Anal Chem 317:300–303
Szadkowski D, Schultze H, Schaller KH, Lehnert G (1985) Arch Hyg 153(1):1–8
Krivan V, Barth P, Morales AF (1993) Mikrochim Acta 110:217–236
Ivicic N, Tomic L, Simeon VI (1985) Arh hig rada toksikol 36:157–164
Perinelli MA, Carugno N (1978) Beiträge zur Tabakforschung International 9(4):214–217
Cogbill EC, Hobbs ME (1957) Tobacco Science 1:68–73
Morie GP, Morrisett PE (1974) Beiträge zur Tabakforschung 7(5):302–304
Scherer G, Barkemeyer H (1983) Ecotoxicology and Environmental Safety 7:71–78
Author information
Authors and Affiliations
Additional information
Dedicated to Professor Dr. Wilhelm Fresenius on the occasion of his 80th birthday
Rights and permissions
About this article
Cite this article
Krivan, V., Schneider, G., Baumann, H. et al. Multi-element characterization of tobacco smoke condensate. Fresenius J Anal Chem 348, 218–225 (1994). https://doi.org/10.1007/BF00325364
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00325364