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Blends of poly(2-hydroxyethyl methacrylate)/ (styrene-co-dialkyl itaconates) and poly(N-vinyl-2-pyrrolidone)/(styrene-co-dialkyl itaconates)

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Summary

Blends containing poly(N-vinyl-2-pyrrolidone) (PVP) and poly(hydroxyethyl methacrylate) (PHEMA) with (styrene-co-dimethyl itaconate) (Sty-co-DMI) and (styrene-co-diethylitaconate) (Sty-co-DEI) copolymers of three different compositions were studied. One Tg value over the whole range of compositions is observed for the majority of the blends, what is indicative of compatibility. The Gordon-Taylor kGT and the Couchman kC parameters were determined for all the blends in order to compare the strength of the interactions. The effect of the side chain structure of the copolymer on the miscibility of these blends is analyzed.

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Authors and Affiliations

  1. Depto. Química Física, Facultad de Química, Pontificia Universidad Católica de Chile, Casilla 306, 22, Santiage, Chile

    Alejandra Opazo, Ligia Gargallo & Deodato Radić

Authors
  1. Alejandra Opazo
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  2. Ligia Gargallo
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  3. Deodato Radić
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Opazo, A., Gargallo, L. & Radić, D. Blends of poly(2-hydroxyethyl methacrylate)/ (styrene-co-dialkyl itaconates) and poly(N-vinyl-2-pyrrolidone)/(styrene-co-dialkyl itaconates). Polymer Bulletin 36, 511–516 (1996). https://doi.org/10.1007/BF00315071

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  • DOI: https://doi.org/10.1007/BF00315071

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