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Electrical and third-order nonlinear optical properties of poly(2-fluoro-1,4-phenylenevinylene) and its copolymers

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Summary

Poly(2-fluoro-1,4-phenylenevinylene), PFPV, and its copolymers have been synthesized via water soluble precursor route and their electrical and optical propreties were measured. It seems that electron-withdrawing fluorine substituent on phenylene ring increases the band-gap of PFPV and it affects electrical and optical properties. The conductivity values of FeCl3-doped drawn polymer films ranged from 10-1 to 101 Scm-1 depending on their composition, and were 10 times larger than those of undrawn ones. The χ(3) value for undrawn PFPV, using THG technique at 1907nm fundamental wavelength, was 4.76x10-12 esu.

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Authors and Affiliations

  1. Department of Chemistry, Korea Advanced Institute of Science and Technology, 373-1 Kusung-Dong, Yusung-Gu, 305-701, Taejon, Korea

    In-Nam Kang & Hong-Ku Shim

  2. Optics Laboratory, Korea Research Institute of Standards and Science, 305-340, Taejon, Korea

    Geon-Joon Lee & Dong-Ho Kim

Authors
  1. In-Nam Kang
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  2. Geon-Joon Lee
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  3. Dong-Ho Kim
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  4. Hong-Ku Shim
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Kang, IN., Lee, GJ., Kim, DH. et al. Electrical and third-order nonlinear optical properties of poly(2-fluoro-1,4-phenylenevinylene) and its copolymers. Polymer Bulletin 33, 89–96 (1994). https://doi.org/10.1007/BF00313478

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  • DOI: https://doi.org/10.1007/BF00313478

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