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Photopolymerization of methyl methacrylate and 2-(dimethylamino) ethyl methacrylate induced by diacetoxyiodobenzene in the presence of radical inhibitors

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Summary

Polyvalent iodine compounds such as diacetoxyiodobenzene, (CH3COO)2IC6H5 (DAI), and bis(trifluoroacetoxy) iodobenzene, (CF3COO)2IC6H5 (BTI), are efficient initiators of cationic and radical polymerizations. To confirm the radical mechanism of DAI-induced polymerization of methyl methacrylate (MMA) and 2-(dimethylamino)ethyl methacrylate (DMAEMA), a study has been performed in the presence of the radical inhibitor 2,3,5,6-tetrachloro-p-benzoquinone (TCQ) and its complex with triethylamine (TEA). The polymerization kinetics and the effect of irradiation intensity have been studied.

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Authors and Affiliations

  1. Department of Chemistry, University of Sofia, BG-1126, Sofia, Bulgaria

    Latchezar Christov & George Georgiev

  2. Department of Chemistry, University of Thessaloniki, GR-540 06, Thessaloniki, Greece

    Irini Sideridou-Karayannidou, George Karayannidis & Anastasios Varvoglis

Authors
  1. Latchezar Christov
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  2. George Georgiev
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  3. Irini Sideridou-Karayannidou
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  4. George Karayannidis
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  5. Anastasios Varvoglis
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Christov, L., Georgiev, G., Sideridou-Karayannidou, I. et al. Photopolymerization of methyl methacrylate and 2-(dimethylamino) ethyl methacrylate induced by diacetoxyiodobenzene in the presence of radical inhibitors. Polymer Bulletin 26, 617–620 (1991). https://doi.org/10.1007/BF00313214

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  • DOI: https://doi.org/10.1007/BF00313214

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