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Mechanisms of exsolution in omphacites from high temperature, type B, eclogites

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Abstract

The microstructural development during the transformation of omphacite into pyroxene-plagioclase symplectites has been studied in some eclogites from the Seve nappe, Central Scandinavian Caledonides. The omphacite transformation can be described as a discontinuous precipitation reaction that occurred in two clearly defined stages to produce a coarser type A, followed by a finer, type B symplectite. Each type has its distinctive chemistry. The combination of microstructural and chemical characteristics of the transformation is used to reconstruct the early stages of the cooling history of the eclogites. In addition, based on a classification of phase transformations according to growth processes, the continuous exsolution reaction reported in high-temperature omphacites is combined with the discontinuous reaction in a time-temperature transformation (TTT) diagram to produce a more unified view of the exsolution in the omphacites.

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References

  • Anderson DL (1977) Composition of the mantle and core. Ann Rev Earth Planet Sci 5:179–202

    Google Scholar 

  • Anderson DL (1979) Chemical stratification of the mantle. J Geophys Res 84:6297–6298

    Google Scholar 

  • Boland JN (1980) Electron microscopy of mineral phase transformations in metamorphic reactions. In: Brederoo P, Boom G (eds) Electron microscopy, vol 1: Physics. North-Holland, Amsterdam, pp 444–451

    Google Scholar 

  • Boland JN, McLaren AC, Hobbs BE (1971) Dislocations associated with optical features in naturally deformed olivine. Contrib Mineral Petrol 30:53–63

    Google Scholar 

  • Carpenter MA (1978) Kinetic control of ordering and exsolution in omphacite. Contrib Mineral Petrol 67:17–24

    Google Scholar 

  • Carpenter MA (1979a) Contrasting properties and behaviour of antiphase domains in pyroxene. Phys Chem Minerals 5:119–131

    Google Scholar 

  • Carpenter MA (1979b) Experimental coarsening of antiphase domains in a silicate mineral. Science 206:681–683

    Google Scholar 

  • Carpenter MA (1980) Mechanisms of exsolution in sodic pyroxenes. Contrib Mineral Petrol 71:289–300

    Google Scholar 

  • Cawthorn RG, Collerson KD (1974) The recalculation of pyroxene endmember parameters and the estimation of ferrous and ferric iron content from electron microprobe analyses. Am Mineral 59:1203–1208

    Google Scholar 

  • Champness PE (1973) Speculation on an order-disorder transformation in omphacite. Am Mineral 58:540–542

    Google Scholar 

  • Champness PE, Lorimer GW (1976) Exsolution in silicates. In: Wenk H-R, Champness PE, Christie JM, Cowley JM, Heuer AH, Thomas G, Tighe NJ (eds) Electron microscopy in mineralogy. Springer, Berlin Heidelberg New York, pp 174–202

    Google Scholar 

  • Champness PE, Cliff G, Lorimer GW (1981) Quantitative analytical electron microscopy. Bull Mineral 104:236–240

    Google Scholar 

  • Cliff G, Lorimer GW (1975) The quantitative analysis of thin specimens. J Microsc 103:203–207

    Google Scholar 

  • Deer WA, Howie RA, Zussman J (1978) Rock-forming minerals, vol 2A: Single chain silicates, 2nd edn. Wiley, New York

    Google Scholar 

  • Ellis DJ, Green DH (1979) An experimental study of the effect of Ca upon garnet-clinopyroxene, Fe-Mg exchange equilibria. Contrib Mineral Petrol 71:13–22

    Google Scholar 

  • Eskola P (1921) On the eclogites of Norway. Vidensk Selsk Skr K1 I, 8:1–118

    Google Scholar 

  • Gasparik T, Lindsley DH (1980) Phase equilibria at high pressure of pyroxenes containing monovalent and trivalent ions. In: Prewitt CT (ed) Pyroxenes. Reviews in mineralogy vol 7. Mineralogical Society of America, Washington, pp 309–339

    Google Scholar 

  • Geisler AH (1951) Precipitation from solid solutions of metals. In: Smulikowski R, Mayer JE, Weyl WA (eds) Phase transformations in solids. Wiley, New York, pp 387–544

    Google Scholar 

  • Green DH, Ringwood AE (1967) An experimental investigation of the gabbro to eclogite transformation and its petrological applications. Geochim Cosmochim Acta 31:767–833

    Google Scholar 

  • Griffin WL, Råheim A (1973) Convergent metamorphism of eclogites and dolerites, Kristiansund area, Norway. Lithos 6:21–40

    Google Scholar 

  • Griffin WL, Austreheim A, Brastad K, Bryhni I, Kril A, Krogh E, Mørk MBE, Qvale H, Torndbakken B (1982) High pressure metamorphism in the Scandinavian Caledonides. In: Gee DG, Sturt BA (eds). The Caledonide Orogen — Scandinavia and related areas. Wiley, New York (in press)

    Google Scholar 

  • Guy AG (1976) Essentials of materials science. McGraw-Hill, New York, Tokyo

    Google Scholar 

  • Hernes I (1954) Eclogite-amphibolite on the Molde Peninsula, Southern Norway. Norsk Geol Tidsskr 33:163–183

    Google Scholar 

  • Holland TJB (1980) The reaction albite-jadeite + quartz determined experimentally in the range 600–1,200° C. Am Mineral 65:129–134

    Google Scholar 

  • Horiuchi S, Gokyu I (1969) Formation of recrystallized grains in heavily rolled sheet — influence of chemical driving force on the formation of recrystallized grains. In: Grewen J, Wasserman G (eds) Textures in research and practice. Springer, Berlin Heidelberg New York, pp 312–318

    Google Scholar 

  • Ito K, Kennedy GC (1974) The composition of liquids formed by partial melting of eclogites at high temperatures and pressures. J Geol 82:383–392

    Google Scholar 

  • Kushiro I (1965) Clinopyroxene solid solutions at high pressures. Ann Rep Dir Geophys Lab Washington Yearb 64:112–117

    Google Scholar 

  • Martin JW, Doherty RD (1976) The stability of microstructures in metals. Cambridge University Press, Cambridge

    Google Scholar 

  • McConnell JDC (1975) Microstructures of minerals as petrogenetic indicators. Ann Rev Earth Planet Sci 3:129–155

    Google Scholar 

  • Mysen BO (1972) Five clinopyroxenes in the Hareidland eclogite Western Norway. Contrib Mineral Petrol 34:315–325

    Google Scholar 

  • Mysen BO, Griffin WL (1973) Pyroxene stoichiometry and the breakdown of omphacite. Am Mineral 58:60–63

    Google Scholar 

  • Nicholson RB, Davies GJ (1971) Development of microstructure. In: Finniston HM (ed) Structural characteristics of materials. Elsevier, Amsterdam, pp 199–289

    Google Scholar 

  • Phakey PP, Ghose S (1973) Direct observation of anti-phase domain structure in omphacite. Contrib Mineral Petrol 39:239–245

    Google Scholar 

  • Putnis A, McConnell JDC (1980) Principles of mineral behaviour. Blackwell, Oxford

    Google Scholar 

  • Ringwood AE (1975) Composition and petrology of the earth's mantle. McGraw-Hill, New York

    Google Scholar 

  • Ringwood AE (1979) Origin of the earth and moon. Springer, Berlin Heidelberg New York

    Google Scholar 

  • Ringwood AE, Green DH (1966) An experimental investigation of the gabbro-eclogite transformation and some geophysical implications. Tectonophysics 3:283–427

    Google Scholar 

  • Roermund HLM van (1982) Eclogites of the Seve Nappe, Jämtland, Central Scandinavian Caledonides. In: Gee DG, Sturt BA (eds) The Caledonide Orogen — Scandinavia and related areas. Wiley, New York (in press)

    Google Scholar 

  • Roermund HLM van, Boland JN (1981) The dislocation substructures of naturally deformed omphacites. Tectonophysics 78:403–418

    Google Scholar 

  • Shewmon PG (1969) Transformations in metals. McGraw-Hill, New York

    Google Scholar 

  • Smyth JR (1980) Cation vacancies and the crystal chemistry of breakdown reactions in kimberlitic omphacites. Am Mineral 65:1185–1191

    Google Scholar 

  • Spry A (1969) Metamorphic textures, Pergamon Press, Oxford

    Google Scholar 

  • Stüwe HP (1978) Driving and dragging forces in recrystallization. In: Haessner F (ed) Recrystallization of metallic materials. Dr. Reidner Verlag. Stuttgart, pp 11–21

    Google Scholar 

  • Vogel DE (1966) Nature and chemistry of the formation of clinopyroxene — plagioclase symplectite from omphacites. Neues Jahrb Mineral Monatsh 6:185–189

    Google Scholar 

  • White S (1973) Dislocation structures responsible for the optical effects in some naturally deformed quartzites. J Mater Sci 8:490–499

    Google Scholar 

  • Wikström A (1970) Electron-microprobe studies of the alteration of omphacite in eclogites from the Nordfjord area, Norway. Norsk Geol Tidssk 50:137–155

    Google Scholar 

  • Williams PF, Zwart HJ (1977) A model for the development of the Seve-Köli Caledonian Nappe Complex. In: Saxena SK, Bhattacharji S (eds) Energetics of geological processes. Springer, New York, pp 169–187

    Google Scholar 

  • Yund RA, McCallister RH (1970) Kinetics and mechanisms of exsolution. Chem Geol 6:5–30

    Google Scholar 

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Boland, J.N., van Roermund, H.L.M. Mechanisms of exsolution in omphacites from high temperature, type B, eclogites. Phys Chem Minerals 9, 30–37 (1983). https://doi.org/10.1007/BF00309467

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