Abstract
Thermal expansion of single-crystal fayalite has been measured by a dilatometric method at temperatures between 25 °C and 850 °C. The results show the presence of anomalous expansion in the b axis, which is correlated to the anomalous variation of elastic moduli with temperature. Grüneisen's parameter is 1.10 and the thermal Debye temperature is 565 K, which is close to the acoustic Debye temperature of 511 K.
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References
Anderson, OL (1966) Derivation of Wachtman's equation for temperature dependence of elastic moduli of oxide compounds. Phys Rev 144:553–557
Chung DH (1971) Elasticity and equation of state of olivines in the Mg2SiO4-Fe2SiO4 system. Geophys J R Astron Soc 25:511–538
Okajima S, Suzuki I, Seya K, Sumino Y (1978) Thermal expansion in single-crystal tephroite. Phys Chem Minerals 3:111–115
Robie RA, Hemingway BS, Fisher JR (1978) Thermodynamic properties of minerals and related substances at 298.15 K and 1 bar (105 Pascals) pressure and at high temperatures. Geol Surv Bull 1452. U.S. Government Printing Office, Washington
Santoro RP, Newnhan RE, Nomura S (1966) Magnetic properties of Mn2SiO4 and Fe2SiO4. J Phys Chem Solids 27:655–666
Simmons G, Wang H (1971) Single crystal elastic constants and calculated aggregate properties: A handbook. MIT Press, Cambridge
Smyth JR (1975) High temperature crystal chemistry of fayalite. Am Mineral 60:1092–1097
Soga N, Anderson OL (1966) High-temperature elastic properties of polycrystalline MgO and Al2O3. J Am Ceram Soc 49:355–359
Sumino Y (1979) The elastic constants of Mn2SiO4, Fe2SiO4, and Co2SiO4, and the elastic properties of olivine group minerals at high temperature. J Phys Earth 27:209–238
Suwa K (1964) Mineralogy of fayalite, with special reference to its thermal and thermodynamical properties. J Earth Sci, Nagoya Univ. 12:129–146
Suzuki I (1975) Thermal expansion of periclase and olivine, and their anharmonic properties. J Phys Earth 23:145–159
Suzuki I, Okajima S, Seya K (1979) Thermal expansion of single-crystal manganosite. J Phys Earth 23:63–69
Takei H (1978) Growth of fayalite (Fe2SiO4) single crystals by the floating-zone method. J Cryst Growth 43:463–468
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Suzuki, I., Seya, K., Takei, H. et al. Thermal expansion of fayalite, Fe2SiO4 . Phys Chem Minerals 7, 60–63 (1981). https://doi.org/10.1007/BF00309452
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DOI: https://doi.org/10.1007/BF00309452