Summary
A simple method of porous volume determination for styrenedivinylbenzene copolymers has been developed. This method is based on water uptake measurements after surface treatment with methanol in order to reduce the characteristic water repellance of the copolymer beads. The porous volume determined by water uptake is in good agreement with mercury porosimetry measurements.
Similar content being viewed by others
References
Millar, J.R.; J. Polym. Sci., Polym. Symp., 68, 167 (1980).
Pepper, K.W.; J. Appl. Chem., I, 124 (1951).
Poinescu, Ig. C.; Beldie, C.; Vlad, C.; J. Appl. Polym. Sci., 29, 23 (1984).
Millar, J.R.; Smith, D.G.; Marr, W.E.; Kressman, T.R.E.; J. Chem. Soc., 218(1963).
Smithwick, R.W.; Powder Tech., 33, 201 (1982).
Poinescu, Ig. C.; Vlad, C.; Carpov, A.; Ioanid, A.; Angew. Makromol. Chem., 156, 105(1988).
Nēgre, M.; Bartholin, M.; Guyot, A.: Angew. Makromol. Chem., 80, 19(1979).
Coutinho, F.M.B.; Rabelo, D.; Eur. Polym. J., 28, 1553 (1992).
Okay, O.; Balkas, T.I.; J. Appl. Polym. Sci., 31, 1785 (1986).
Rabelo, D.; Coutinho, F.M.B. In preparation.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Rabelo, D., Coutinho, F.M.B. Porous volume determination of styrene-divinylbenzene copolymers by water uptake measurements. Polymer Bulletin 30, 725–728 (1993). https://doi.org/10.1007/BF00300043
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00300043