Skip to main content
Log in

Preparation of Porous Polymer Networks of N-Vinylpyrrolidone with Triethylene Glycol Dimethacrylate and Determination of Their Specific Surface Area Using Rose Bengal Dye

  • Macromolecular Compounds and Polymeric Materials
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Porous polymer networks of N-vinylpyrrolidone with triethylene glycol dimethacrylate were prepared by three-dimensional radical copolymerization using template approach based on incorporation of macromolecular nanoobjects with porogen function. The adsorption of Rose Bengal dye from aqueous solutions onto the copolymers prepared and its desorption were studied by electronic absorption spectroscopy. The specific surface area of the porous polymer networks was estimated from the Rose Bengal adsorption data. The porous polymer networks adsorb riboflavin from aqueous solution. The riboflavin desorption is characterized by complex pattern due to washout from pores of different size.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Gendrikson, O.D., Zherdev, A.V., and Dzantiev, B.B., Russ. Biol. Chem. Rev., 2006, vol. 46, pp. 149–192.

    Google Scholar 

  2. Vlakh, E.G., Korzhikov, V.A., Hubina, A.V., and Tennikova, T.B., Russ. Chem. Rev., 2015, vol. 84, no. 9, pp. 952–980.

    Article  CAS  Google Scholar 

  3. Silverstein, M.S., Polymer, 2014, vol. 55, no. 1, pp. 304–320.

    Article  CAS  Google Scholar 

  4. Dawson, R., Cooper, A.I., and Adams, D.J., Prog. Polym. Networks, 2012, vol. 37, pp. 530–563.

    Article  CAS  Google Scholar 

  5. Nguyen, C., Hawker, C.J., Miller, R.D., et al., Macromolecules, 2000, vol. 33, no. 11, pp. 4281–4284.

    Article  CAS  Google Scholar 

  6. Hedrick, J.L., Trollsas, M., Hawker, C.J., et al., Macromolecules, 1998, vol. 31, no. 25, pp. 8691–8705.

    Article  CAS  Google Scholar 

  7. Plummer, C.J.G., Garamszegi, L., Nguyen, T.Q., et al., J. Mater. Sci., 2002, vol. 37, no. 22, pp. 4819–4829.

    Article  CAS  Google Scholar 

  8. Kurmaz, S.V., Grubenko, G.A., Knerelman, E.I., et al., Mendeleev Commun., 2014, vol. 24, no. 2, pp. 125–127.

    Article  CAS  Google Scholar 

  9. Fadeeva, N.V., Kurmaz, S.V., Knerelman, E.I., et al., Russ. Chem. Bull., 2016, vol. 65, no. 8, pp. 2089–2096.

    Article  CAS  Google Scholar 

  10. Fadeeva, N.V., Kurmaz, S.V., Knerelman, E.I., et al., Polym. Sci., Ser. B, 2017, vol. 59, no. 3, pp. 257–267.

    Article  CAS  Google Scholar 

  11. McKeown, N.B. and Budd, P.M., Macromolecules, 2010, vol. 43, no. 12, pp. 5163–5176.

    Article  CAS  Google Scholar 

  12. Vlasova, I.M., Polyansky, D.V., Vlasov, A.A., and Saletsky, A.M., Moscow Univ. Phys. Bull., 2013, vol. 68, no. 3, pp. 231–234.

    Article  Google Scholar 

  13. Kebets, P.A., Leonenko, Y.V., Malosemov, M.V., and Nesterenko, P.N., Moscow Univ. Chem. Bull., 2006, vol. 61, no. 3, pp. 46–49.

    Google Scholar 

  14. Ishchenko, A.A. and Shapovalov, S.A., J. Appl. Spectrosc., 2004, vol. 71, no. 5, pp. 605–629.

    Article  CAS  Google Scholar 

  15. Pyryaev, A.N. and Kurmaz, S.V., Russ. J. Appl. Chem., 2012, vol. 85, no. 8, pp. 1247–1254.

    Article  CAS  Google Scholar 

  16. Orlowska, M., Koutchma, T., Grapperhaus, M., et al., Food Bioprocess Technol., 2012, vol. 6, no. 6, pp. 1580–1592.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. V. Kurmaz.

Additional information

Original Russian Text © S.V. Kurmaz, N.V. Fadeeva, E.I. Knerel’man, G.I. Davydova, 2018, published in Zhurnal Prikladnoi Khimii, 2018, Vol. 91, No. 1, pp. 115−122.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kurmaz, S.V., Fadeeva, N.V., Knerel’man, E.I. et al. Preparation of Porous Polymer Networks of N-Vinylpyrrolidone with Triethylene Glycol Dimethacrylate and Determination of Their Specific Surface Area Using Rose Bengal Dye. Russ J Appl Chem 91, 105–112 (2018). https://doi.org/10.1134/S1070427218010172

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427218010172

Navigation