Abstract
Atomic Force Microscopy (AFM) images have been recorded from the surfaces of platelet type monocrystals of linear alkanes, n-tritriacontane, C33H68, and n-hexatriacontane, C36H74. Structural details have been revealed in the range from several hundreds of nanometers down to the atomic scale. High resolution AFM micrographs of the linear alkanes show a regular pattern of elevations characterized by two main periodicities: aAFM=.70±.02 nm, bAFM=.52±.05 nm, \(\gamma _{AFM} = 88 \pm 3^\circ ,\), and aAFM=.79±.05 nm, bAFM=.61±.05 nm, \(\gamma _{AFM} = 87 \pm 3^\circ\), for C33H68 and C36H74 respectively. This structure is in fair agreement with the orthorhombic subcell of the bulk structure as confirmed by electron diffraction. Further, AFM results are in accordance with an orthorhombic unit cell for C33H68, and a monoclinic one for C36H74 under investigation. Consequently, the elevations in the AFM images can be assigned to individual methyl groups, which form the surface layer of a paraffine crystal. A regular surface structure has also been observed in AFM images of platelet crystals of cyclic alkanes, cyclooctatetracontane (CH2)48, and cyclodoheptacontane (CH2)72. In these cases, the periodicities are characterized by aAFM=1.10±.01 nm, bAFM=.85±.01 nm, yAFM=89±1o, and aAFM=1.11±.06 nm, bAFM=.91±.05, and \(\gamma _{AFM} = 90 \pm 3^\circ \), for (CH2)48 and (CH2)72, respectively. The images are consistent with the arrangement of the adjacent reentry folds obtained from crystallographic data.
Similar content being viewed by others
References
Binnig G, Rohrer H, Gerber Ch, Weibel E (1982) Phys Rev Lett 49:52
Binnig G, Quate C F, Gerber Ch (1986) Phys Rev Lett 56:930
Scanning Tunneling Microscopy and Related Methods' Böhm R, Garcia N, Rohrer H (eds) (1990) Kluwer Acad Publ, Dordrecht
Magonov S N, Schuchhardt J, Kempf S, Keller E, Cantow H-J (1991) Synth Met 40:59
Magonov S N, Kempf S, Rotter H, Cantow H-J (1991) Synth Met 40:73
Magonov S N, Bar G, Keller E, Yagubskii E B, Cantow H-J (1991) Synth Met 40:247
Magonov S N, Bar G, Laukhina E E, Yagubskii E B, Cantow H-J (1991) in prep
Magonov S N, Qvarnström K, Elings V, Cantow H-J (1991) Polym Bull in press
Lotz B, Stocker W, Wittmann J C, Magonov S N, Cantow H-J (1991) Polym Bull in press
Magonov S N, Bar G, Cantow H-J, Bauer H-D, Müller I, Schwoerer M (1991) Polym Bull in press
Möller M, Cantow H-J, Drotloff H, Emeis D, Lee K-S, Wegner G (1987) Makrom Chem 187:1237
Schill G, Zürcher C, Fritz H (1978) Chem Ber 111:2901
Keller E J (1989) J Appl Crystallogr 22:19
Strobl G, Ewen B, Fischer E W, Piesczek (1974) J Chem Phys 61:5257
Shearer H M M, Vand V (1956) Acta Cryst 9:379
Gould S, Marti O, Drake B, Hellemans L, Bracker C E, Hansma P K, Keder N L, Eddy M M, Stucky G D (1988) Nature 332:332
Teare P W (1959) Acta Cryst 12:19
Trzebiatowski T, Dräger M, Strobl G R (1982) Macromol Chem 183:731
Author information
Authors and Affiliations
Additional information
Herrn Prof. Dr. Harald Cherdron zu seinem 60. Geburtstag herzlich gewidmet
Rights and permissions
About this article
Cite this article
Stocker, W., Bar, G., Kunz, M. et al. Atomic force microscopy on polymers and polymer related compounds. Polymer Bulletin 26, 215–222 (1991). https://doi.org/10.1007/BF00297530
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00297530