Summary
1-(2-Hydroxyethyl)aziridine as nucleophilic monomer was copolymerized in the absence of an initiator under various experimental conditions with acrylamide as electrophilic monomer. All copolymers were characterized by elemental analysis, IR, and 1H-NMR spectroscopy. The viscosity measurements showed that the copolymers behave as polyelectrolytes. The copolymer composition was determined from elemental analysis and 1H-NMR spectra.
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References
T. Saegusa (1977) Angew. Chem. Int. Ed. Engl. 16: 826.
T. Saegusa (1975) CHEMTECH 5: 295.
T. Saegusa, S. Kobayashi, Y. Kimura, H. Ikeda (1975) J. Macromol. Sci. Chem., A9: 641.
T. Saegusa, S. Kobayashi, Y. Kimura (1976) Pure Appl. Chem., 48: 307.
T. Balakrischnan, M. Periyasami (1980) Makromol. Chem. Rapid Commun., 1: 307.
G. Odian, P. A. Gunatillake (1984) Macromolecules 17: 1297.
B.L. Rivas, G.S. Canessa, S.A. Pooley (1989) Eur. Polym. J. 25: 255.
G. Odian, P.A. Gunatillake, D. Tomalia (1985) Macromolecules 18: 605.
T. Saegusa, S. Kobayashi, Y. Kimura (1974) Macromolecules 7: 139.
B.L. Rivas, S.A. Pooley (1983) An. Quim. 79: 62.
B.L. Rivas, G.S. Canessa, S.A. Pooley (1986) Makromol. Chem. 187: 71.
B.L. Rivas, G.S. Canessa, S.A. Pooley (1987) Makromol. Chem. 188: 149.
B.L. Rivas, G.S. Canessa, S.A. Pooley (1989) Makromol. Chem. 190: 2665.
T. Saegusa, S. Kobayashi, Y. Kimura, M. Ikeda, S. Hirayanagi (1973) 22th Polymer Symp. Soc. Polym. Sci. Japan.
C.I. Simionescu, M. Grigoras, E. Bicu, G. Onofrei (1985) Polym. Bull. 14: 79.
B.L. Rivas, G. del C. Pizarro (1989) Eur. Polym. J. 25: 1001.
B.L. Rivas G del C. Pizarro (1988) Polym. Bull. 19: 123.
B.L. Rivas, G. del C. Pizarro (1989) Eur. Polym. J., 25: 1227.
B.L. Rivas, G.S. Canessa, S.A. Pooley (1990) Polym. Bull., 23: 171.
B.L. Rivas, G.S. Canessa, S.A. Pooley (1983) Polym. Bull., 9: 417.
B.L. Rivas, G.S. Canessa, S.A. Pooley (1985) Polym. Bull., 13: 65.
“Organikum” (1972) VEB Deutscher Verlag der Wissenschaften Berlin.
T. Saegusa, S. Kobayashi, Y. Kimura (1975) Macromolecules 8: 374.
R.M. Fuoss, P. Strauss (1948) J. Polym. Sci., 3: 246.
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Rivas, B.L., Concha, I. Copolymerization without initiator of 1-(2-hydroxyethyl)aziridine and acrylamide. Polymer Bulletin 30, 191–197 (1993). https://doi.org/10.1007/BF00296849
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DOI: https://doi.org/10.1007/BF00296849