Summary
Agarose water solutions of different concentrations and agarose-guar water solutions of 1% (w/w) total concentration and varied compositions were submitted to viscometric and turbidimetric measurements as function of the temperature. Phase diagrams for both systems are compared. For agarose solutions, phase separation occurs prior to gelation within a certain concentration range, and network formation seems to take place by the connectivity of the polymer-rich domains. For the mixed agarose-guar system, the homogeneous solutions gel directly.
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McCleary BV, Dea ICM, Windust J, Cooke D (1984) Carbohydr Polym 4: 253
Tako M, Nakamura S (1985) Carbohydr Res 138: 207
Cuvelier G, Launay B (1988) Carbohydr Polym 8:271
Lopes L, Andrade C, Milas M, Rinaudo M, Carbohydr Polym (in press)
Flory P J (1953) Principles of Polymer Chemistry, 6th edn., Cornell University Press, Ithaca New York
Erman B, Monnerie L (1989) Macromolecules 22: 3342
de Gennes PG (1979) Scaling Concepts in Polymer Physics, Cornell University Press, Ithaca London
Coniglio A, Stanley HE, Klein W (1982) Phys Rev B 25: 6805
Pines E, Prins W (1973) Macromolecules 6: 888
Arnott S, Fulmer A, Scott WE, Dea ICM, Moorhouse R, Rees DA (1974) J Mol Biol 90: 269
Rochas C, Rinaudo M (1984) Biopolymers 23: 735
Watase M, Nishinari K (1986) Polym J 18: 1017
Rochas C (1987) F Hydrocolloids 1: 215
Ross-Murphy SB (1987) F Hydrocolloids 1: 485
Rochas C, Lahaye M (1989) Carbohydr Polym 10: 289
Baines ZV, Morris E R (1987) F Hydrocolloids 1: 197
Nishi T, Wang T T, Kwei T K (1975) Macromolecules 8: 227
Watase M, Nishinari K (1988) Polymer J 20: 1125
San Biagio PL, Bulone D, Emanuele A, Madonia F, Di Stefano L, Giacomazza D, Trapanese M, Palma-Vitorelli M B, Palma M U (1990) Makromol Chem, Macromol Symp 40:33
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Andrade, C.T., Garcia, R.B. & Abritta, T. Viscometric and transmitted light investigation of agarose and agarose-guar water systems. Polymer Bulletin 27, 297–304 (1991). https://doi.org/10.1007/BF00294535
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DOI: https://doi.org/10.1007/BF00294535