Summary
Two mono-functional macromonomers of poly (propylene oxide-b-ethylene oxide) were synthesized by reaction with methacryloyl chloride. The macromonomers have the same molecular weight and ratio of ethylene oxide and propylene oxide sequences. The reactive methacrylate group can be linked to the ethylene oxide (BuPPOPEO) or to the propylene oxide (BuPEOPPO). These macromonomers showed self-gelling in one week even at low temperature and under a dry atmosphere. Graft copolymers were obtained by reaction of these macromonomers with methyl methacrylate upon free-radical initiation and they were characterized by GPC, VPO, IR and 1H NMR spectra.
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References
Clinton N, Matlock P (1986) 1,2 Epoxide Polymers. In: Mark H-F (ed.) Encyclopedia of Polymer Science and Engineering. John Wiley and Sons, New York (vol 6, pp 257–258)
Rempp P, Franta E (1986) Polym Prep 27:181
Hoffmann H, Ebert G (1988) Angew Chem Int Ed Engl 27:902
Oliveira C-M-F, Gomes, A-S (1989) Polym Bull 22: 401
Levesque G, Moitié V, Bacle B, Depraétère P (1988) Polymer 29:2271
Niwa M, Hayashi T, Matsumoto T (1986) J Macromol Sci Chem 23:433
Gramain P, Frère Y (1986) Polym Commun 27:16
Gramain P, Frère Y (1987) Makromol Chem 188:593
Tsukahara Y, Hayadri N, Irang X, Yamashita Y (1989) Polym J 21:377
Sanches N-B Private communication
Delpech M-C Private communication
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Oliveira, C.M.F., Lucas, E.F. Graft copolymers of poly(methyl methacrylate) backbone and poly(propylene oxide-b-ethylene oxide) branches. Polymer Bulletin 24, 363–370 (1990). https://doi.org/10.1007/BF00294088
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DOI: https://doi.org/10.1007/BF00294088