Skip to main content
SpringerLink
Log in

Functionalization of suluble polymers

1. Replacement of the hydroxyl groups of poly(oxyethylene) by amino groups

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

In a first example of the functionalization of soluble polymers the conversion of the hydroxyl groups of poly(oxyethylene) into primary amino groups has been studied. Starting from poly(oxyethylene), the preparation of the diphthalimido derivative via the disodium salt is described. Prom this regiospecific functionalized polymer the di(aminoethyl) poly(oxyethylene), which exhibits excellent solubility properties, can be obtained by polymeranalogous hydrazinolysis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • ABUCHOWSKI, A., T. VAN ES, N.C. PALZCUK and P. F. DAVIS: J. Biol. Chem. 252, 3578 (1977)

    Google Scholar 

  • BARNES, J.H., G.F. ESSLEMONT and P. HOLT: Makromol. Chem. 176, 275 (1975)

    Google Scholar 

  • BATZ, H.G.: Adv. Polym. Sci, 23, 26 (1977)

    Google Scholar 

  • BAYER, E., and K. GECKELER: Liebigs Ann. Chem. 1974, 1671

  • BAYER, E., and M. MUTTER: Nature(London) 237, 512 (1972)

    Google Scholar 

  • DRAKE, N.L.: J. Amer. Chem. Soc. 71, 2426 (1949)

    Google Scholar 

  • GECKELER, K., and E. BAYER: Makromol. Chem. 175, 1995 (1974a)

    Google Scholar 

  • GECKELER, K., and E. BAYER: Int. Symp. Macromol. (IUPAC), Rio de Janeiro, 1974b

  • HOLT, P., and C. THADANI: Makromol. Chem. 169, 55 (1963)

    Google Scholar 

  • HOLZBACH, G., and E. BAYER: Angew. Chem. 89, 120 (1977)

    Google Scholar 

  • MARSHALL, J.J., and M.L. RABINOWITZ: J. Biol. Chem. 251, 1081 (1976)

    Google Scholar 

  • MUTTER, M.: Tetrahedron Lett. 31, 2839 (1978)

    Google Scholar 

  • SALZBERG, P.L.: Org. Synth., Coll. Vol. 1, 119 (1932)

    Google Scholar 

  • WYKES, J.R., P. DUNNILL and M.P. LILLY: Biochem. Biophys. Acta 250, 522 (1971)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institut für Organische Chemie der Universität, 7400, Tübingen, Federal Republic of Germany

    Kurt Geckeler

Authors
  1. Kurt Geckeler
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Geckeler, K. Functionalization of suluble polymers. Polymer Bulletin 1, 427–431 (1979). https://doi.org/10.1007/BF00284414

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00284414

Keywords

Search

Navigation