Skip to main content
SpringerLink
Log in

Circular dichroism study

Palladium (II) complexes with polymer bound S-methyl-L-cysteine

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

N methacryloyl-S-methyl-L-cysteine (SMC) homopolymer along with a copolymer with methacrylic acid were prepared in the purpose of studying their complexation with Pd(II). The circular dichroism study showed that the binding of SMC residue to a polymeric chain does not change the coordination donor set of Pd complexation, i.e. ¦N, s ¦. The number of side chains per metal ion involved in the complexation depends on the molar fraction of SMC in the case of the copolymer and on the SMC/Pd ratio for both homopolymer anc copolymer. The variation of viscosity when adding Pd(II) suggests the formation of intramolecular loops.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • DAVANKOV V.A., ROGOZHIN, S.V. and SEMECHKIN, A.V.: J. Chromat. 91, 493 (1974).

    Google Scholar 

  • DECOCK-LE REVEREND, B., LOUCHEUX, C., KOWALIK, T. and KOZLOWSKI, H.: Inorg. Chim. Acta 66, 205 (1982).

    Google Scholar 

  • HADJILIADIS, N., THEODOROU, V., PHOTAKI, I., GELLERT, R.W. and BAU, R.: Inorg. Chim. Acta 60, 1 (1982).

    Google Scholar 

  • IMANISHI, Y. and KINIWA, H.: Polymer 22, 1548 (1981).

    Google Scholar 

  • JEZOWSKA-TRZEBIATOWSKA, B., FORMICKA-KOZLOWSKA, G. and KOZLOWSKI, H.: Bull. Acad. Pol. Sci. Ser. Sci. Chim. 26, 561 (1978) and references therein.

    Google Scholar 

  • KOIDE, M., SUGANUMA, N.S., TSUCHIDA, E. and KURIMURA, Y.: Makromol. Chem. 182, 1391 (1981).

    Google Scholar 

  • KOWALIK, T., KOZLOWSKI, H. and DECOCK-LE REVEREND, B.: Inorg. Chim. Acta 67, 5 (1982).

    Google Scholar 

  • KOZLOWSKI, H., SIATECKI, Z., JEZOWSKA-TRZEBIATOWSKA, B. and ALLAIN, A.: Inorg Chim. Acta 46, L25 (1980).

    Google Scholar 

  • KOZLOWSKI, H., DECOCK-LE REVEREND, B., DELARUELLE, J.L., LOUCHEUX, C. and ANCIAN, B.: Ibid 78, 31 (1983).

    Google Scholar 

  • KUBIAK, M., ALLAIN, A., JEZOWSKA-TRZEBIATOWSKA, B., GTOWIAK, T. and KOZLOWSKI, H.: Acta Cryst. B36, 2246 (1980).

    Google Scholar 

  • KULKAMI, R.K. and MORAWETZ: J. Polym. Sci. 54, 491 (1961).

    Google Scholar 

  • LIM, M.C. and MARTIN R.B.: J. inorg. Nucl. Chem. 38, 1911 (1976).

    Google Scholar 

  • MARTIN, R.B. in “Metal ions in Biological Systems” H. SIGEL Ed., N.Y. BASEL vol. 9 Chap. 4 (1974).

  • SNYDER, R.V., ANGELICI, R.J. and MECK, R.B.: J. Am. Chem. Soc. 94, 2660 (1972).

    Google Scholar 

  • TSUCHIDA, E., NISHIKAWA, H. and TERADA E.: Europ. Polym. J. 12, 611 (1976).

    Google Scholar 

  • TSUCHIDA, E. and NISHIDE, H.: Adv. Polym. Sci. 24, 1 (1977).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire de chimie macromoléculaire, Laboratoire associé au C.N.R.S. No 351, Université des Sciences et Techniques de Lille, F-59655, Villeneuve d'Ascq Cedex, France

    Michèle Delporte, Brigitte Decock -Le Reverend & Claude Loucheux

  2. Institute of Chemistry, University of Wroclaw, Joliot Curie 14, PL-50-383, Wroclaw, Poland

    Henryk Kozlowski

Authors
  1. Michèle Delporte
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Brigitte Decock -Le Reverend
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Claude Loucheux
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Henryk Kozlowski
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Delporte, M., Reverend, B.D.L., Loucheux, C. et al. Circular dichroism study. Polymer Bulletin 10, 351–356 (1983). https://doi.org/10.1007/BF00281947

Download citation

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00281947

Keywords

Search

Navigation