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Reply to “criticism hypotheses by Gandini and Cheradame regarding the initiation of carbocationic polymerization” (Pol. Bull. 10, 141 1983)

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Summary

The mechanism of grafting and blocking in cationic polymerisations initiated by the system RCl-Et2AlCl is discussed. The criticism by Kennedy and Wondraczek of the proposal of a grafting-onto (and blocking-onto) mechanism given in our book is refuted point by point and new arguments are put forward to corroborate our original hypothesis.

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References

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Authors and Affiliations

  1. Laboratoire de Chimie Macromoléculaire et Papetière, Ecole Française de Papeterie, B.P. 65, F-38402, Saint-Martin d'Hères-Cedex, France

    Hervé Cheradame & Alessandro Gandini

Authors
  1. Hervé Cheradame
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  2. Alessandro Gandini
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Cheradame, H., Gandini, A. Reply to “criticism hypotheses by Gandini and Cheradame regarding the initiation of carbocationic polymerization” (Pol. Bull. 10, 141 1983). Polymer Bulletin 10, 303–310 (1983). https://doi.org/10.1007/BF00281940

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  • DOI: https://doi.org/10.1007/BF00281940

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