Abstract
The example of methanesulfonyl halides has shown the possibility of initiating cationic polymerization of 2-oxazolines by alkylsulfonic acid halides. Chain propagation rate constants and activation energy of the processes have been determined. The kinetic mechanisms suggest a slow initiation of polymerization followed by fast chain propagation. It has been shown that the polymerization of 2-ethyl-2-oxazoline initiated by aliphatic sulfonyl halides proceeds predominantly at the active centers of the ionic type. The synthesis of oligo(3-sulfonyl)methacrylate-graft-poly(2-isopropyl-2-oxazoline) is described as an example of using alkylsulfonyl halides for graft copolymers.
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Original Russian Text © A.N. Blokhin, M.P. Kurlykin, A.B. Razina, M.M. Dudkina, A.V. Ten’kovtsev, 2018, published in Vysokomolekulyarnye Soedineniya, Seriya B, 2018, Vol. 60, No. 4, pp. 269–274.
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Blokhin, A.N., Kurlykin, M.P., Razina, A.B. et al. Alkylsulfonyl Halides as Initiators of Cationic Polymerization of Oxazolines. Polym. Sci. Ser. B 60, 421–426 (2018). https://doi.org/10.1134/S1560090418040012
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DOI: https://doi.org/10.1134/S1560090418040012