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Stability conditions for polymer dielectrics in uniform electric field

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Summary

A classical model system consisting of the polymer molecules under the influence of a homogeneous external electric field is presented. A set of Lagrange equations of motion, characterized by only the nearest interactions of the atoms, are formulated. From them, the stability conditions for a polymer, defining a pre-breakdown phenomenon in the presence of an external homogeneous electric field, are derived.

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Authors and Affiliations

  1. Department of Physical Chemistry, Faculty of Chemical Technology, Slovak Technical University, Jánska 1, CS-812 37, Bratislava, Czechoslovakia

    L. Valko

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  1. L. Valko
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Valko, L. Stability conditions for polymer dielectrics in uniform electric field. Polymer Bulletin 9, 144–151 (1983). https://doi.org/10.1007/BF00275582

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  • DOI: https://doi.org/10.1007/BF00275582

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