Skip to main content
SpringerLink
Log in

Phase diagram and conductivity of the polymer electrolyte: PEORLiCF3SO3

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

A simple model for the concentration dependence of the electrical conductivity of the polymer electrolyte: poly(ethyleneoxide) — LiCF3SO3 is presented. It is assumed that the crystals with stoichiometry: 4 polymer oxygens to 1 lithiumion are insulating and the surrounding conducting solution is saturated in the 4∶1 crystals. Correcting the space available for conduction with a volume correction factor accounts qualitatively for the concentration dependence of the conductivity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • Armand, M.B., Chabagno, J.M. and Duclot, M.J.: Abstract 6.5 Extended Abstracts, 2nd Int. Conf. on Solid Electrolytes, St. Andrews, Scotland, Sept. 20–22. 1978

  • Armand, M.B., Chabagno, J.M., Duclot, M.J.: “Polyethers as electrolytes” in ‘Fast Ionic Transport in Solids’. Edited by Mundy Vashishta. Elsevier, North-Holland, 1979

  • Owen, J.: “Advanced Batteries and Fuel Cells”. Proc. of the second contractors meeting. The European Committee R & D programme (1979–1982): Energy Conservation. P.54. Ed. by Ehringer, H. et al.

  • Papke, B.L., Dupon, R., Ratner, M.A., Shriver, D.F.: Solid State Ionics 5, 685 (1981)

    Google Scholar 

  • Shriver, D.F., Papke, B.L., Ratner, M.A., Dupon, R., Wong, T. Brodwin, M.: Solid State Ionics 5, 83 (1981)

    Google Scholar 

  • Sørensen, P.R., Jacobsen, T.: submitted to Solid State Ionics (1982)

  • Weston, J.E. and Steele, B.C.H.: Solid State Ionics 2, 347 (1981)

    Google Scholar 

  • Weston, J.E. and Steele, B.C.H.: Solid State Ionics 7, 81 (1982)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemistry Department, RISØ National Laboratories, DK-4000, Roskilde, Denmark

    Poul Ravn Sørensen

  2. Fysisk Kemisk Institut, The Technical University of Denmark, DK-2800, Lyngby, Denmark

    Torben Jacobsen

Authors
  1. Poul Ravn Sørensen
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Torben Jacobsen
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sørensen, P.R., Jacobsen, T. Phase diagram and conductivity of the polymer electrolyte: PEORLiCF3SO3 . Polymer Bulletin 9, 47–51 (1983). https://doi.org/10.1007/BF00275567

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00275567

Keywords

Search

Navigation