Summary
Three branched star-like poly(γ-benzyl-l-glutamate) was synthesized using three functional amine as an initiator, and characterized through light-scattering, ORD and intrinsic viscosity measurements. Experimental results suggest that the synthesized star-like poly(γ-benzyl-l-glutamate)s are composed of three branches of equal length.
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References
E.Eliezer and A.Silberberg, Biopolymers 5,95(1967).
E.Eliezer and A.Silberberg, Biopolymers 5,105 (1967).
J.P.Williot, J.M.Ruysschaert and J.Jaffe, J.Polym.Sci. (Phys) 10,2125(1972).
M.Sakamoto and Y.Kuroyanagi, J.Polym.Sci. (Chem) 16,1107(1978).
M.Sakamoto, Y.Kuroyanagi and R.Sakamoto, J.Polym.Sci. (Chem) 16,2001(1978).
E.R.Blout and R.H.Karlson, J.Am.Chem.Soc. 78,941(1956).
D.J.Coumou, J.Colloid Sci. 15,408(1960).
B.H.Zimm, J.Chem.Phys. 16,1093(1948).
B.H.Zimm, J.Chem.Phys. 16,1099(1948).
W.Moffitt and J.T.Yang, Proc.Natl.Acad.Sci. (USA) 42,596(1956).
T.Hayashi and A.Nakajima, Bull.Inst.Chem.Res.Kyoto Univ. 46,62(1968).
P.Doty and J.T.Yang, J.Am.Chem.Soc. 78,498(1956).
B.H.Zimm, P.Doty and K.Iso, Proc.Natl.Acad.Sci. (USA) 45,1601(1959).
H.Fujita, A.Teramoto and K.Nakagawa, J.Chem.Phys. 46,4179(1967).
T.Matsumoto and A.Teramoto, Biopolymers 13,1347(1974).
T.Norisuye, Thesis, Osaka University(1975).
P.Doty, J.H.Bradbury and A.M.Holtzer, J.Am.Chem.Soc. 78,947(1956).
H.Yamakawa, J.Chem.Phys. 48,3845(1968).
P.J.Flory and T.G.Fox, J.Am.Chem.Soc. 73,1904(1951).
B.H.Zimm and R.W.Kilb, J.Polym.Sci. 37,19(1959).
B.H.Zimm, J.Chem.Phys. 24,269(1956).
M.Morton, T.E.Helminiak, S.D.Gadkary and F.Buche, J.Polym.Sci. 57,471(1962).
B.H.Zimm and W.H.Stockmayer, J.Chem.Phys. 17,1301(1949).
M.Kurata and M.Fukatsu, J.Chem.Phys. 41,2934(1964).
P.J.Flory, “Statistical Mechanics of Chain Molecules”, John Wiley & Sons, Inc., New York(1969).
M.Oka and A.Nakajima, Polymer J. 9,573(1977).
M.Oka and A.Nakajima, Polymer J. 9,583(1977).
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Oka, M., Nakajima, A. Synthesis and characterization of three-branched star-like poly(γ-benzyl-l-glutamate). Polymer Bulletin 11, 447–451 (1984). https://doi.org/10.1007/BF00265486
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DOI: https://doi.org/10.1007/BF00265486