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Synthesis of networks in solution

1. Influence of the gelation on the crosslink kinetics

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Summary

The kinetics of the solution crosslink process of polybutadiene is studied using a bistriazolinedione as crosslink agent. Beyond the gel point strong deviations from the pre-gel kinetics are observed due to the hindered translational diffusion in the gel.

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Authors and Affiliations

  1. Instituto do Quimica, Universidade Federal do Rio Grande do sul, Av.Bento Gonçalves 10600, 90.000, Porto Alegre, Brasil

    L. L. de Lucca Freitas, M. Maldaner Jacobi & R. Stadler

  2. Institut für Makromolekulare Chemie der Universität Freiburg, Stefan-Meier-Strasse 31, D-7800, Freiburg i. Brsg., Germany

    R. Stadler

Authors
  1. L. L. de Lucca Freitas
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  2. M. Maldaner Jacobi
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  3. R. Stadler
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de Lucca Freitas, L.L., Jacobi, M.M. & Stadler, R. Synthesis of networks in solution. Polymer Bulletin 11, 407–414 (1984). https://doi.org/10.1007/BF00265479

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  • DOI: https://doi.org/10.1007/BF00265479

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