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Radical copolymerization of optically active acryloyl-d-phenylglycine methyl ester with methyl methacrylate or with methyl acrylate in optically active solvent

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Summary

The rate of radical copolymerization of optically active acryloyl-d-phenylglycine methyl ester (APM) with methyl methacrylate (MMA) or with methyl acrylate(MA) was dilatometrically measured in optically active solvents, D-or L-ethyl mandelate. The copolymerization rate of D-monomer in D-solvent was higher than that in L-solvent. The origin of the difference in the copolymerization rate was discussed using data of UV and 13C-NMR chemical shift and spin lattice relaxation time, T1, and the asymmetric solvent effect was concluded to be due to the difference in the interaction between propagating radical and solvent.

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Authors and Affiliations

  1. Department of Macromolecular Science, Faculty of Science, Osaka University, Toyonaka, 560, Osaka, Japan

    Mikiharu Kamachi, Yoko Kuwae & Shun-ichi Nozakura

  2. Department of Chemistry, Faculty of Engineering Science, Osaka University, Toyonaka, 560, Osaka, Japan

    Koichi Hatada

Authors
  1. Mikiharu Kamachi
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  2. Yoko Kuwae
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  3. Shun-ichi Nozakura
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  4. Koichi Hatada
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Kamachi, M., Kuwae, Y., Nozakura, Si. et al. Radical copolymerization of optically active acryloyl-d-phenylglycine methyl ester with methyl methacrylate or with methyl acrylate in optically active solvent. Polymer Bulletin 10, 98–100 (1983). https://doi.org/10.1007/BF00263245

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  • DOI: https://doi.org/10.1007/BF00263245

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