Summary
An intramolecular charge transfer complex (CTC) was obtained by radical copolymerization of N-(2-hydro-xyethyl) carbazolyl acrylate with 2′-ethylacryl-4, 5, 7-trinitro-9-fluorenone-2-carboxylate. The copolymerization mechanism is simple terminal, and the obtained CTC does not present decomplexation even at high temperatures. This is the first intramolecular CTC containig both carbazole- and trinitrofluorenone-substituted structural units.
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Simionescu, C.I., Percec, V. & Natansohn, A. Intramolecular charge transfer complexes. Polymer Bulletin 3, 551–557 (1980). https://doi.org/10.1007/BF00256298
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DOI: https://doi.org/10.1007/BF00256298