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Plasma-induced polymerization

5. Bulk copolymerization of methacrylonitrile with styrene

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Summary

High molecular weight methacrylonitrile (M1) — styrene (M2) copolymers were obtained by plasma-induced bulk copolymerization. The reactivity ratios, determined by Kelen — Tüdös method, were shown to be r1=0.21 and r2=0.34 and indicate a radical mechanism of polymerization. Some microstructural aspects of the obtained copolymers are presented.

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Authors and Affiliations

  1. “P.Poni” Institute of Macromolecular Chemistry, 6600, Jassy, Romania

    Almeria Natansohn

  2. Department of Organic and Macromolecular Chemistry, Polytechnic Institute, 6600, Jassy, Romania

    Bogdan C. Simionescu, Almeria Natansohn, Monica Leancă, Carmen Ananiescu & Cristofor I. Simionescu

Authors
  1. Bogdan C. Simionescu
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  2. Almeria Natansohn
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  3. Monica Leancă
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  4. Carmen Ananiescu
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  5. Cristofor I. Simionescu
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Simionescu, B.C., Natansohn, A., Leancă, M. et al. Plasma-induced polymerization. Polymer Bulletin 4, 569–576 (1981). https://doi.org/10.1007/BF00256283

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  • DOI: https://doi.org/10.1007/BF00256283

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