Summary
The copolymer composition equation based on the intramolecular cyclization and the intermolecular propagation model for the copolymerization of 1,6-dienes and monoolefins was applied to the radical copolymerization of diallyl ether and sulfur dioxide. The ratio of the rate constants of the heteropropagation and the cyclization of the uncyclized diallyl ether radical,rb,was 0.72±0.10 in benzene and 0.60±0.10 in DMSO at 45 °C.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
AMEMIYA,Y.,KATAYAMA,M. and HARADA,S.:Makromol.Chem.178,2499(1977)
BUTLER,G.B.:J.Polym.Sci.48,279(1960)
FUJIMORI,K. and KHOO,M.:Makromol.Chem.179,859(1978)
FUJIMORI,K.:Makromol.Chem.179,2867(1978)
SCHONIGER,W.:Mikrochim.Acta 1956,869
SOLOMON,D.H. and HAWTHORNE,D.G.:Macromol.Sci.,Rev.Macromol.Chem.15, 143(1976)
YOUNG,L.J.:in HAM, G.E. ed. Copolymerization, New York, Interscience 1964, page 845
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Fujimori, K. Copolymer composition in the cyclocopolymerization of diallyl ether with sulfur dioxide. Polymer Bulletin 4, 491–495 (1981). https://doi.org/10.1007/BF00255706
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00255706