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Syntheses and polymerizations of macromers

I. Synthesis of p-vinylbenzyloxyl poly(tetrahydrofuran) macromer and its radical polymerization

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Summary

Living poly(tetrahydrofuran) (PTHF) was coupled with sodium p-vinylbenzyloxide quantitatively to prepare a macromer of p-vinylbenzyloxyl poly(tetrahydrofuran) (VBO-PTHF). The radical polymerization of the macromer with AIBN was performed. From the GPC measurement the conversion of the macromer to poly-macromer was shown to be high percentage, but the degree of polymerization of poly-macromer was much lower than that expected in the case of regular monomers such as styrene.

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References

  • ASAMI, R. and NAKASHIMA, M., Polym. Prepr. (Jpn), 24 No. 1, 191 (1975)

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  • MEERWEIN, H., Org. Syn., 46, 113 (1966)

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  • NITADORI, Y. and TSURUTA, T., Kobunshi (high polymers), 28, 192 (1979)

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Authors and Affiliations

  1. Department of Synthetic Chemistry, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, 466, Nagoya, Japan

    Ryuzo Asami, Mikio Takaki, Kazuo Kita & Eiji Asakura

Authors
  1. Ryuzo Asami
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  2. Mikio Takaki
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  3. Kazuo Kita
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  4. Eiji Asakura
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Asami, R., Takaki, M., Kita, K. et al. Syntheses and polymerizations of macromers. Polymer Bulletin 2, 713–718 (1980). https://doi.org/10.1007/BF00254457

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  • DOI: https://doi.org/10.1007/BF00254457

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