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Copolymerization of polyurethane macromer with 2-hydroxyethyl methacrylate: NMR kinetic study

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Summary

The copolymerization kinetics of Polyurethane containing a vinylic bond with 2-hydroxyethyl methacrylate in solution was investigated. The reaction was studied using a JEOL-PS-100 spectrometer at various temperatures and concentration conditions. The a and b exponents in the equation for the overall polymerization rate, Rp=const[M]a[I]b were determined. The reaction products were analyzed by means of 1H-NMR and turbidimetric titration.

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References

  • LABANA, S.S., J.Polym.Sci. 6, A-1, 3283 (1968)

    Google Scholar 

  • SPIRIN, Yu.L. et al., Patent U.S.S.R. No.273424 (1970)

  • GUDZERA, S.S., SPIRIN, Yu.L., and MAGDINEC, V.V. Sintez i Fizikokhimya Polimerov 21, 15 (1977)

    Google Scholar 

  • GUDZERA, S.S., SPIRIN, Yu.L., and MAGDINEC, V.V., and RUDKO, A.R., ibid.--Sintez i Fizikokhimya Polimerov 18, 9 (1976)

  • VAN GEET, A.L., Anal.Chem. 40, 2227 (1968).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Macromolecular Chemistry, Czechoslovak Academy of Sciences, 162 06, Prague 6, Czechoslovakia

    S. Hudeček, J. Spěváček, I. Hudečková & J. Mikešová

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  1. S. Hudeček
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  2. J. Spěváček
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  3. I. Hudečková
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  4. J. Mikešová
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Hudeček, S., Spěváček, J., Hudečková, I. et al. Copolymerization of polyurethane macromer with 2-hydroxyethyl methacrylate: NMR kinetic study. Polymer Bulletin 3, 143–149 (1980). https://doi.org/10.1007/BF00254165

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  • DOI: https://doi.org/10.1007/BF00254165

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