Skip to main content
SpringerLink
Log in

Effect of hindered piperidine derivatives on polypropylene photooxidation

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

The photostabilizing effect of a hindered piperidine derivative was studied in the photooxidation of polypropylene films by following the formation of carbonyl and hydroperoxide groups, as well as the change of concentration of the stabilizer. This additive — the tetramethylpiperidine sebacate — proved to be more effective than hydroxybenzophenone, hydroxybenztriazole or a sulphur containing nickel complex, since no oxidation products were formed after irradiation with 20O Mlxh dose.

Addition of the piperidine derivative together with hydroxybenztriazole or with the organic nickel complex was less effective than with hydroxybenzophenone. In latter case concentration of both stabilizers under irradiation decreased at a slower rate than in the case of separate application. The effect of Cyasorb UV 531 and Tinuvin 770 was additive and the spontaneous rupture of the samples took place only after a long period of irradiation (∼ 250 Mlxh).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • BÁLINT, G., KELEN, T., REHÁK, Á. and TÜDŐS, F.: React. Kin. Cat. Letters 4, 467 (1976)

    Google Scholar 

  • BONKOWSKI, J.E.: Text. Res. 39, 243 (1969)

    Google Scholar 

  • CARLSSON, D.J. and WILES, D.M.: Macromol. 2, 587 (1969)

    Google Scholar 

  • CARLSSON, D.J. and WILES, D.M.: J. Polym. Sci., Polym. Chem. Ed. 12, 2217 (1974)

    Google Scholar 

  • CHAKRABORTY, K.B. and SCOTT, G.: Chem. and Ind. 237, (1978)

  • CICCHETTI, O.: Adv. Polym. Sci. 7, 70 (1970)

    Google Scholar 

  • GERVITS, L.L., ZOLOTOVA, N.V. and DENISOV, E.T.: Vysokomol. Soed. Kratk. Soob. A18, 408 (1976)

    Google Scholar 

  • GUILLORY, J.P. and COOK, C.F.: J. Polym. Sci., Polym. Chem. Ed. 11, 1927 (1973)

    Google Scholar 

  • HESKINS, M. and GUILLET, J.E.: Macromol. 1, 97 (1968)

    Google Scholar 

  • LÁSZLÓ-HEDVIG, S., IRING, M., BÁLINT, G., KELEN, T. and TÜDŐS, F.: IUPAC Macromol. Symp. on Long-term Properties of Polymers, Stockholm, 1976; J. Appl. Polym. Sci., in press

  • PÁC, J., SEDLAR, J., PETRUJ, J. and PARIZEK, M.: Plaste u. Kaut. 22, 724 (1975)

    Google Scholar 

  • SAVIDES, C.: SPE J. 29, 38 (1973)

    Google Scholar 

  • SHLIAPINTOKH, V.A., BISTRITSKAIA, E.V., SHAPIRO, A.B., SMIRNOV, L.N. and ROZANTSEV, E.G.: Izv. Akad. Nauk. SSSR, Ser. Khim. 1915 (1973)

  • SHLIAPINTOKH, V.A., IVANOV, V.B., KHVOSTACH, O.M., SHAPIRO, A.B. and ROZANTSEV, E.G.: Dokl. Akad. Nauk. SSSR, Ser. Khim. 225, 1132 (1975)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Central Research Institute for Chemistry of the Hungarian Academy of Sciences, 1525, Budapest, Hungary

    G. Bálint, T. Kelen, F. Tüdös & Á. Rehák

Authors
  1. G. Bálint
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. Kelen
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. F. Tüdös
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Á. Rehák
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bálint, G., Kelen, T., Tüdös, F. et al. Effect of hindered piperidine derivatives on polypropylene photooxidation. Polymer Bulletin 1, 647–652 (1979). https://doi.org/10.1007/BF00254145

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00254145

Keywords

Search

Navigation