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Mono- and binuclear ruthenium(II) trifluoroacetato complexes containing monodentate co-ligands

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Summary

The syntheses of new dinuclear and mononuclear complexes of RuII trifluoroacetate containing monodentate co-ligands, namely [Ru2(μ-O2CCF3)4L2] (L = py, 2-Mepy or 3-Mepy); trans-[Ru(O2CCF3)2L4] (L = 2-Mepy or 3-Mepy); [Ru(O2CCF3)(PPh3)4](O2CCF3) and [Ru(O2CCF3)2(CO)(MPh3)3] (M = P or As), are described. The complexes have been characterized by physical and electrochemical studies.

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References

  1. G. Jia, A. L. Rheingold, B. S. Haggerty and D. W. Meek, Inorg, Chem., 31 900 (1992), and refs cited therein.

    Google Scholar 

  2. T. A. Stephenson and G. Wilkinson, J. Inorg. Nucl. Chem., 28, 2285 (1966).

    Google Scholar 

  3. A. Spencer and G. Wilkinson, J. Chem. Soc., Dalton Trans., 786, (1974), and refs cited therein.

  4. A. J. Lindsay, M. Motevalli, M. B. Hursthouse and G. Wilkinson, J. Chem. Soc., Dalton Trans., 2321 (1985).

  5. S. D. Robinson and M. F. Uttley, J. Chem. Soc., Dalton Trans., 1912 (1973).

  6. F. A. Cotton, V. M. Miskowski and B. Zhong, J. Am. Chem. Soc., 111, 6177 (1989).

    Google Scholar 

  7. M. C. Barral, R. Jimenez-Aparicio, M. J. Larrubia, E. C. Royer and F. A. Urbanos, Inorg. Chem. Acta, 186, 239 (1991).

    Google Scholar 

  8. E. A. Seddon and K. R. Seddon, The Chemistry of Ruthenium, Elsevier, Amsterdam, 1984.

    Google Scholar 

  9. E. Lindner, R. Fawzi, W. Hiller, A. Carvill and M. McCann, Chem. Ber., 124, 2691 (1991).

    Google Scholar 

  10. R. A. Sanchez-Delgado, J. S. Bradley and G. Wilkinson, J. Chem. Soc., Dalton. Trans., 399 (1976).

  11. R. Noyori, Chem. Soc. Rev., 18, 187 (1989).

    Google Scholar 

  12. A. J. Lindsay, G. Wilkinson, M. Motevalli and M. B. Hurst-house, J. Chem. Soc., Dalton Trans., 2723 (1987).

  13. A. Cogne, E. Belorizky, J. Laugier and P. Rey, Inorg. Chem., 33, 3364 (1994).

    Google Scholar 

  14. A. Dobson, S. D. Robinson and M. F. Uttley, J. Chem. Soc., Dalton Trans., 370 (1975).

  15. A. Dobson and S. D. Robinson, Inorg. Chem., 16, 1321 (1977).

    Google Scholar 

  16. P. B. Critchlow and G. Wilkinson, Inorg. Chem., 17, 1902 (1978).

    Google Scholar 

  17. E. B. Boyar, A. Dobson, S. D. Robinson, B. L. Haymore and J. C. Huffman, J. Chem. Soc., Dalton Trans., 621 (1985).

  18. A. R. Al-Ohaly, R. A. Head and J. F. Nixon, J. Chem. Soc., Dalton Trans., 889 (1978).

  19. M. O. Albers, D. C. Liles, E. Singleton and J. E. Yates, J. Organometal. Chem., 272, C62 (1984).

    Google Scholar 

  20. D. A. Tocher, R. O. Gould, T. A. Stephenson, M. A. Bennett, J. P. Ennett, T. W. Matheson, L. Sawyer and V. K. Shah, J. Chem. Soc., Dalton Trans., 1571 (1983).

  21. E. C. Morrison, C. A. Palmer and D. A. Tocher, J. Organometal. Chem., 349, 405 (1988).

    Google Scholar 

  22. J. W. Steed and D. A. Tocher, Inorg. Chim. Acta, 189, 135 (1991).

    Google Scholar 

  23. J. G. Norman Jr, G. E. Renzoni and D. A. Case, J. Am. Chem. Soc., 101, 5256 (1979).

    Google Scholar 

  24. J. G. Grasselli and W. H. Ritchey, Atlas of Spectral Data and Physical Constants for Organic Compounds, 2nd Edit., CRC Press, Inc., Cleveland, 1975, Vol. IV.

    Google Scholar 

  25. R. H. Prince and K. A. Raspin, J. Chem. Soc. A, 612 (1969).

  26. A. B. P. Lever, Inorganic Electronic Spectroscopy, Elsevier, Amsterdam, 1984, p. 334.

    Google Scholar 

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Sarkhel, P., Sarker, S.C., Gupta, A.K. et al. Mono- and binuclear ruthenium(II) trifluoroacetato complexes containing monodentate co-ligands. Transition Met Chem 21, 250–253 (1996). https://doi.org/10.1007/BF00165977

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  • DOI: https://doi.org/10.1007/BF00165977

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