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Synthesis, characterization and reactivity studies of dichloroacetylacetonato acetylacetone ruthenium(III)

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Summary

The RuIII complex [RuCl2(acac)(acacH)] (acacH = acetylacetone) was isolated in high yield by reacting RuCl3 with acacH. The compound was used as a convenient starting material for the synthesis of a variety of RuIII complexes, viz. [RuCl2(acac)L2] (L = PPh3, AsPh3, py, MeCN, Me2SO, o-phenylenediamine; L2 = phen or bipy) and M2[RuCl4(acac)] (M = Me4N, Rb or Cs). The compounds were characterized by physicochemical and spectroscopic methods.

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Authors and Affiliations

  1. Department of Chemistry, North-Eastern Hill University, Bijni Complex, 793 003, Shillong, India

    Bipul C. Paul & Raj K. Poddar

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  1. Bipul C. Paul
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  2. Raj K. Poddar
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Paul, B.C., Poddar, R.K. Synthesis, characterization and reactivity studies of dichloroacetylacetonato acetylacetone ruthenium(III). Transition Met Chem 18, 96–100 (1993). https://doi.org/10.1007/BF00136061

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