The heat capacity of molybdenum chalcogenides with different Sn/Ga content was measured at temperatures of T ≤ 60 K. The occurrence of two phases of the chalcogenides studied could clearly be seen for higher Ga concentrations. In the miscibility gap there coexists a superconducting phase (T c= 12.5 K) SnGa0.25Mo5S6 with the ferromagnetic GaMo5S6 phase (T curie = 19 K). As for the pure ternary compound GaMo5S6, a singularity of the heat capacity could also be observed in the range of the structural change (T = 45 K). All the singularities are discussed.
Similar content being viewed by others
References
M. Marezio, P. D. Dernier, J. P. Remeika, E. Corenzwit, and B. T. Matthias, Mat. Res. Bull. 8, 657 (1973); O. Bars, J. Guillevic, and D. Grandjean, J. Sol. State Chem. 7, 158 (1973).
J. G. Booth, N. Morton, and S. W. Young, J. Less-Common Metals 40, 353 (1975).
ø. Fischer, in Proc. 14th Int. Conf. Low Temp. Phys. (North-Holland, Amsterdam, 1975), p. 172; S. Foner, E. J. McNiff, and E. J. Alexander, Phys. Lett. 49A, 269 (1974).
R. W. McCallum, D. C. Johnston, R. N. Shelton, W. A. Fertig, and M. B. Maple, Solid State Comm. 24, 501 (1977).
N. E. Alekseevskii, C. Bazan, N. M. Dobrovolskii, V. I. Nizhankovskii, V. I. Tsebro, and V. M. Zakosarenko, Phys. Lett. 54A, 371 (1975).
N. E. Alekseevskii, N. M. Dobrovolskii, and V. I. Tsebro, Sov. Phys.—JETP Lett. 23, 694 (1976).
N. E. Alekseevskii, N. M. Dobrovolskii, V. I. Nizhankovskii, and V. I. Tsebro, Sov. Phys.—JETP 73, 1045 (1977).
N. E. Alekseevskii, N. M. Dobrovolskii, V. I. Tsebro, and V. F. Schamrai, Sov. Phys.— JETP 24, 417 (1976).
H. Barz, Mat. Res. Bull. 8, 983 (1973); N. E. Alekseevskii, in Symposium “Physical Properties of Solids in High Magnetic Fields” (Wrocŀaw, Poland, 1978), p. 37.
E. P. Wohlfarth, J. Appl. Phys. 39, 1061 (1968).
J. H. E. Griffiths, J. Owen, and I. M. Ward, Proc. Roy. Soc. A 219, 526 (1953).
N. E. Alekseevskii, N. M. Dobrovolskii, and V. I. Tsebro, Sov. Phys.—JETP Lett. 20, 59 (1974); 20, 465 (1974).
G. Wolf, K. Bohmhammel, K. Siegel, and H. G. Schmidt, Exp. Techn. Phys. 4, 483 (1977).
K. Bohmhammel, H. Mädge, and G. Wolf, Cryogenics 17, 553 (1977).
G. Wolf, Doctoral Thesis, Bergakademie Freiberg, GDR (1975).
N. E. Alekseevskii, N. M. Dobrovolskii, G. Wolf, and C. Hohlfeld, to be published.
O. K. Andersen, W. Klose, and H. Nohl, Phys. Rev. B 17, 1209 (1978).
J. Hatta and W. Rehwald, J. Phys. C: Solid State Phys. 10, 2075 (1977); R. A. Craven, F. J. DiSalvo, and F. S. L. Hsu, Solid State Comm. 25, 39 (1978); R. A. Craven and S. F. Meyer, Phys. Rev. B 16, 4583 (1978).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Alekseevskii, N.E., Wolf, G., Tsebro, V.I. et al. Specific heat capacity of molybdenum chalcogenides. III. Measurements of the heat capacity of Sn1 − x Ga x Mo5S6. An investigation of the singularities at low temperatures. J Low Temp Phys 38, 243–252 (1980). https://doi.org/10.1007/BF00115278
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00115278