Summary
This paper traces the complete time history of a spatially homogeneous model of a branched-chain reaction through asymptotic methods and develops (i) a subcritical solution (fizzle) where the state variables change by small amounts, and (ii) a supercritical solution (explosion) where extremely rapid transients occur. Three distinct time scales are seen to govern the explosion: a long induction period exhibiting a very slow change of state (as in a thermal explosion), a very brief period characterized by a rapid increase in the chain-carrier concentration but a small increase in temperature (unlike a thermal explosion), followed by a longer period in which most of the chemical heat is released.
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References
N. N. Semenov, Some problems in chemical kinetics and reactivity, Vol. 2, Princeton University Press, Princeton, New Jersey (1959).
F. S. Dainton, Chain reactions, an introduction, Methuen and Company, London (1966).
N. N. Semenov, Zür Theorie des Verbrennungs-prozesses, Zeitschrift für Physik, 48 (1928) 571–583.
D. A. Frank-Kamenetskii, Diffusion and heat exchange in chemical kinetics, Princeton University Press, Princeton, New Jersey (1955).
D. R. Kassoy, Extremely rapid transient phenomena in combustion, ignition and explosion, SIAM-AMS Proceedings, 10 (1976) 61–72.
R. A. Strehlow, Fundamentals of combustion, International Textbook Company, Scranton, Pennsylvania (1968).
F. A. Williams, Combustion theory, Addison-Wesley Publishing Company, Reading, Massachusetts (1965).
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This research was supported by the U. S. Army Research Office, Durham under Grant DAAG 29-76-G-0253.
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Kapila, A.K. Homogeneous branched-chain explosion: Initiation to completion. J Eng Math 12, 221–235 (1978). https://doi.org/10.1007/BF00036460
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DOI: https://doi.org/10.1007/BF00036460