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Molecular Interactions from the Experimental and Validation with Estimated Theoretical Sound Velocity

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Abstract

The ultrasonic velocity, density and viscosity measurements carried out for the binary mixtures of toluene, m-xylene with some butanols at 303 K. Various theoretical models have been applied to these binary systems; evaluate the sound velocity values and compared with the experimental values. The validity of Nomoto theory (NT), Van Deal-Vangeal (IMR) and Free length theory (FLT) is checked and a comparative study of the above models is made. The non-ideal behavior of the system is explained in terms of molecular interactions of the constituents of the mixture. The interactions further, evident with percentage deviation, molecular interaction parameter and goodness fit test.

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References

  1. Ali A, Nain AK (2001) Study of intermolecular interaction in binary mixture of formamide with 2-propanol, 1,2-propanediol and 1,2,3-propandeol through ultrasonic speed measurement. Ind J Pure Appl Phys 39:421

    CAS  Google Scholar 

  2. Kannappan V (2009) Determination of stability constants of charge transfer complexes of iodine monochloride and certain ethers in solutions at 303 K by ultrasonic method. Ind J Pure Appl Phys 1(1):5–10

    Google Scholar 

  3. Nain AK (2008) Ultrasonic and viscometric studies of molecular interaction in binary mixtures of formamide with ethanol, 1-proponal, 1,2, ethanediol, and 1,2, proponediol, at different temperatures. J Mol Liq 140(1):108

    Article  CAS  Google Scholar 

  4. Agnihotri PK, Adgaonkar CS (1989) Theoretical evaluation of ultrasonic velocity in binary liquid mixtures. Ultrasonics 27:248–251

    Article  CAS  Google Scholar 

  5. Nayeem SM, Kondaiah M, Sreekanth K, Krishna Rao D (2015) Comparative study of molecular interaction in aromatic, cyclic and aliphatic ketones with 1-octanol at 303.15 K: an insight from ultrasonic velocity and density. J Mol Liq 207:286–293

    Article  CAS  Google Scholar 

  6. Rathnam MV (2012) Molecular interaction study of binary mixtures of methyl benzoate, viscometric and ultrasonic study. J Mol Liq 166:9–16

    Article  CAS  Google Scholar 

  7. Nomoto O (1958) Empirical formula for sound velocity in liquid mixtures. J Phys Soc Jpn 13:1528–1532

    Article  CAS  Google Scholar 

  8. Van Deal W, Vangeal E (1969) In: Proceeding of the First International Conference on Calorimetry and thermodynamics, Warsaw, pp 555

  9. Jacobson B (1952) Intermolecular free length in the liquid state - I, adiaabtic and isothermal compressibilities. Acta Chem Scand 6:1485–1498

    Article  CAS  Google Scholar 

  10. Jacobson B (1951) Intermolecular free length in liquids in relation to compressibilities, surface tension and viscosity. Acta Chem Scand 5:1214–1216

    Article  CAS  Google Scholar 

  11. Patil SS, Mirgane SR, Arbad BR (2014) Excess molar volume and deviations in viscosities of binary liquid mixtures of acrylic esters with hexane-1-ol at 303.15 and 313.15K. J Saudi Chem Soc 18:945–952

    Article  Google Scholar 

  12. Pearson K (1978) Fundamental of mathematical statistics S. Chand & Company, New Delhi, p 903

    Google Scholar 

  13. Rowlinson JS (1959) Liquids and Liquid mixtures. Butter Worth Scientific Publishing, London

    Google Scholar 

  14. Reddy KC, Subramaniyam SV, Bhimsenachar J (1964) Thermodynamics of binary liquid mixtures containing cyclohexane part -1. J Phys Soc Jpn 19:559–566

    Article  CAS  Google Scholar 

  15. Rama Rao GV, Viswanatha Sarma V, Siva Krishna J, Rambabu C (2005) Theoretical evaluation of ultrasonic velocities in binary liquid mixtures of 0-chlorophenol at different temperatures. Indian J Pure Appl Phys 43:345–354

    Google Scholar 

  16. Nithiyanantham S (2019) Ultrasonic velocity models in (micro and nano fluids): theoretical validations. Int Nano Lett 9(2):89–97

    Article  Google Scholar 

  17. Nithiyanantham S (2017) Ultrasonic velocity models in liquids (nano fluids). J Comput Theor Nanosci 14:2077–2082

    Article  CAS  Google Scholar 

  18. Nithiyanantham S, Palaniappan L (2011) Estimation of theoretical sound velocity in the (Bio ternary) liquid systems (a-amylase + Galactose) at 298.15 K. Arab J Sci Eng 36(4):655–661

    Article  CAS  Google Scholar 

  19. Nayeem SkMd, Kondaiah M, Sreekanth K, Krishna Rao D (2014) Ultrasonic investigations of molecular interaction in binary mixtures of cyclohexane with isomers of butanols. J Appl Chem 2014:741795

    Article  Google Scholar 

  20. Karunakar T, Srinivas CH (2013) Thermo Acoustic and Infrared study of molecular interactions in binary mixtures aniline + 1-butanols. Res Rev J Pure Appl Phys 1(1):5–10

    Google Scholar 

  21. Gowrisankar M, Sivarambabu S, Venkateswarlu P, Kumar KS (2012) Excess volumes speeds of sound, isentropic compressibilities and viscosity of binary mixtures of N-ethylaniline with some aromatic ketones at 303.15 K. Bull Korean Chem Soc 33(5):1686–1692

    Article  CAS  Google Scholar 

  22. Rathnam MV, Mankumare S, Jain K, Kumar MS (2012) Densities, viscosities and speeds of sound of binary mixtures of ethyl 1—benzoate hydrocarbon sat. J Solut Chem 41(2012):475–490

    Article  CAS  Google Scholar 

  23. Satyanarayana GR, Sujatha K, Begum Z, Rambabu C (2014) Evaluation and comparative study of theoretical ultrasonic velocities in binary liquid mixtures of o-chloro phenol with alkoxyethanols at different temperatures and atmospheric pressure. Phys Chem Ind J 9(8):283–291

    CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Physics, Annamalai University, Annamalainagar, Chidambaram, Tamilnadu, 602008, India

    L. Palaniappan

  2. Post Graduate and Research Department of Physics, Thiru. Vi. Kalyanasundaram Govt Arts and Science College, Thiruvaur, Tamilnadu, 610003, India

    S. Nithiyanantham

Authors
  1. L. Palaniappan
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  2. S. Nithiyanantham
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Correspondence to S. Nithiyanantham.

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Palaniappan, L., Nithiyanantham, S. Molecular Interactions from the Experimental and Validation with Estimated Theoretical Sound Velocity. Chemistry Africa 3, 277–285 (2020). https://doi.org/10.1007/s42250-019-00091-w

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  • DOI: https://doi.org/10.1007/s42250-019-00091-w

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