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Molecular Interaction and Physico-Chemical Analysis in Ternary Organic Molecules (Toluene + Chloroform + Cyclohexane) at Various Temperatures

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Abstract

Thermo-dynamical analyses towards the organic mixtures are necessary in all industry. The ultrasonic sound velocity (U), measurements in ternary organic mixtures (Toluene + Chloroform + Cyclohexane) have been carried out at 303.15 to 313.15 K. The experimental/derived datas used to compute the deviations for their excess values to investigate and confirming the type of interactions. With this derived parameters to get excess parameters calculated and used to further reconfirming the type, strength, magnitude and further possible interactions such as complex formation, dipole–dipole and dispersions types are interpreted and discussed. In addition the ideal and non-ideal behavior is also analyzed. The Ultrasonic velocity data are with some recent and familiar models and a comparative study of the above models is made to ensure the possible type of interactions among the mixtures.

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Acknowledgements

The authors gratefully acknowledge, Dr. K. Ganesan, Prof & Head, (Retd), TBML College, Porayar, Tamilnadu, India inspired this complete work.

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Authors and Affiliations

  1. Ultrasonics/Bio Physics Divisions, Post Graduate and Research Department of Physics, Thiru Vi. Ka. Govt Arts College, Thiruvarur, 610003, India

    S. Nithiyanantham & S. Mullainathan

  2. Department of Physics, AVC College of Engineering, Mayiladuthurai, Tamil Nadu, 609309, India

    V. Vanathi

  3. Post Graduate and Research Department of Physics, Ethiraj College for Women, Chennai, Tamilnadu, 600008, India

    S. Mahalakshmi

  4. Department of Physics, Annamalai University, Annamalai Nagar, Chidambaram, Tamilnadu, 602008, India

    L. Palaniappan

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  1. S. Nithiyanantham
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  2. V. Vanathi
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  3. S. Mullainathan
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  4. S. Mahalakshmi
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  5. L. Palaniappan
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Correspondence to S. Nithiyanantham.

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Nithiyanantham, S., Vanathi, V., Mullainathan, S. et al. Molecular Interaction and Physico-Chemical Analysis in Ternary Organic Molecules (Toluene + Chloroform + Cyclohexane) at Various Temperatures. Chemistry Africa 5, 849–854 (2022). https://doi.org/10.1007/s42250-022-00377-6

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  • DOI: https://doi.org/10.1007/s42250-022-00377-6

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