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Fabrication of Polyether Sulfone Blend Imprinted Membranes for Selective Adsorption of p-hydroxybenzonic from Salicylic Acid

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Abstract

Highly selective polyether sulfone (PES) blend imprinted membranes for template p-hydroxybenzonic (p-HB) were synthesized by phase inversion imprinting technique using polybenzimidazoles (PBI) as a functional polymer and nanosized Al2O3 as the additives. The SEM analysis showed that cross-sectional morphology of membranes were strongly influenced by the content of nano-sized Al2O3. Compared with PES1-MIM, PES2-MIM and PES4-MIM, the PES3-MIM containing 2.0 wt.% nano-sized Al2O3 exhibited higher membrane flux, kinetic equilibrium adsorption value, binding capacity and better selectivity for p-HB. The experimental data of adsorption kinetic were well fitted to the pseudo-secondorder kinetic model using multiple regression analysis. Static adsorption isotherm experiments exhibited that the PES3-MIM had the maximum adsorption capacity for p-HB. Moreover, selective experiment showed that the selectivity coefficients of PES3-MIM for p-HB relative to salicylic acid (SA) was 3.670, showing that PES3-MIM had excellent binding affinity and selectivity for separating p-HB form p-HB-contained aqueous solution.

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Authors and Affiliations

  1. Research Center of Analysis and Measurement, Kunming University of Science and Technology, Kunming, 650000, China

    Xiaolei Li & Chaofen Yang

  2. The Research Institute of Resources Insects of the Chinese Academy of Forestry, Kunming, 650000, China

    Jun Chen

Authors
  1. Xiaolei Li
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  2. Jun Chen
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  3. Chaofen Yang
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Correspondence to Xiaolei Li.

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Li, X., Chen, J. & Yang, C. Fabrication of Polyether Sulfone Blend Imprinted Membranes for Selective Adsorption of p-hydroxybenzonic from Salicylic Acid. Fibers Polym 19, 977–986 (2018). https://doi.org/10.1007/s12221-018-1106-4

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  • DOI: https://doi.org/10.1007/s12221-018-1106-4

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